Isotopic Enrichment of Nickel in Aqueous Solution/Crown Ether System
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概要
- 論文の詳細を見る
The isotopic enriching process of the nickel isotopes by the liquid-liquid extraction using a crown ether of dicyclohexano-18-crown-6 was investigated. The nickel chloride exists simply as the aqua complex in the aqueous phase, not as the chloro complex even in the concentrated salt solution. The extraction reaction is supposed to be, Ni2+(6H2O)+L+2Cl-=NiLCl2+6H2O, where L represents the crown ether, and Ni2+(6H2O) and NiLCl2 denote the 6 hydrated nickel ion and the crown ether complex of nickel, respectively. The unit mass enrichment factor, εu=0.0017-0.0026 was small compared with that of zinc isotopes. The odd/even isotope effect was recognized to be as large as εO/E=0.018. The enrichment factor was reviewed at the correlation with the isotope shift of atomic spectra and the hyperfine structure splitting of 61Ni.
- 日本質量分析学会の論文
- 1997-08-01
著者
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NOMURA Masao
Research Laboratory for Nuclear Reactors, Tokyo Institute of Technology
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Yamamoto Tadashi
Department of Structural Pathology Institute of Nephrology, Graduate School of Medical and Dental Sc
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Yamamoto Tadashi
Department Of Cardiology Kouseikai Hospital
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Nomura Masao
Research Laboratory For Nuclear Reactors Tokyo Institute Of Technology
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Fujii Toshiyuki
Department Of Pathology Kansai Medical University:pharmacology Division National Cancer Research Ins
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Yamamoto T
Mitsubishi Electric Corp.
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NISHIZAWA Kazushige
Department of Nuclear Engineering, Graduate School of Osaka University
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MIKI Takahito
Department of Nuclear Engineering, Graduate School of Osaka University
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IKEDA Ryuusuke
Department of Nuclear Engineering, Graduate School of Osaka University
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Miki Takahito
Department Of Nuclear Engineering Osaka University
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Ikeda Ryuusuke
Department Of Nuclear Engineering Graduate School Of Osaka University
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Nishizawa Kazushige
Department Of Nuclear Engineering Osaka University
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Nishizawa Kazushige
Department Of Nuclear Engineering Graduate School Of Engineering Osaka University
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Fujii Toshiyuki
Department Of Innovative And Engineered Materials Tokyo Institute Of Technology
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Fujii Toshiyuki
Department Of Nuclear Engineering Graduate School Of Osaka University
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Yamamoto Takao
Department Of Nuclear Engineering Osaka University
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Yamamoto Tadashi
Departmanets of Structural Pathology, Institute of Nephrology, Graduate School of Medical and Dental Sciences, Niigata University
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