Isotope effects in electrolytic formation of lithium amalgam.
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概要
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Isotope effects in the lithium amalgam formation were studied by using the mercury cathode and LiOH solutions. The electrolyses were carried out at different conditions of both applied voltages 4-10 V, and the concentrations of initially charged LiOH, mol/dm3. Higher efficiency of electrolytic amalgam formation was observed at higher LiOH concentrations and higher applied voltages. At these conditions, however, significant amount of solid amalgam was produced in the mercury phase. From the isotopic analyses on the samples taken during the electrolyses, it was found that the isotopic equilibrium was attained between the aqueous and the liquid amalgam phases. The isotopic equilibrium constant (isotope separation factor) was determined as 1.056 (average value for all the experiments) at 20°C.
- 一般社団法人 日本原子力学会の論文
著者
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Fujii Yasuhiko
Research Laboratory For Nuclear Reactors Tokyo Institute Of Technology
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Nomura Masao
Research Laboratory For Nuclear Reactors Tokyo Institute Of Technology
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OKAMOTO Makoto
Research Laboratory for Nuclear Reactors Tokyo Institute of Technology
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FUJIE Makoto
Research Laboratory for Nuclear Reactors Tokyo Institute of Technology
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