Curve fitting methods applied to the elucidation of asymmetric gas-liquid chromatographic peaks.
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概要
- 論文の詳細を見る
It was shown that the shape of gas-liquid chromatographic peak is expressed by the Gaussian distribution multiplied by a higher order algebraic equation of time. Application of the curve fitting methods, <I>i.e.</I>, the Newton's divided-difference formula and the orthogonal polynomials method, could well clear up the experimentally observed gas-liquid chromatograms of trailing and leading types, respectively. The asymmetric shapes of gas-liquid chromatographic peaks are attributed to the slowness of vaporization or dissolution in the partition process.
- 公益社団法人 日本化学会の論文
著者
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Kambara Tomihito
Department Of Chemistry Faculty Of Science Hokkaido University
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Takeuchi Koji
Department of Air Pollution Control, National Research Institute for Pollution and Resources
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