Reaction of Iron(III)-Form Ion Exchanger with Acetylacetone
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概要
- 論文の詳細を見る
It was found that ferric ions are removed from resin by acetylacetone(Hacac) to form trisacetylacetonatoiron-(III), Fe(acac)<SUB>3</SUB>. By the addition of a small amount of pyridine-water mixture to the iron(III)-form resin in acetylacetone milieu, the ferric ions are quantitatively removed from the resin, and in their place the pyridinium ions are adsorbed onto it. The reaction was successfully applied to the synthesis of Fe(acac)<SUB>3</SUB> in over 95% yield.
- 公益社団法人 日本化学会の論文
著者
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Ohzeki Kunio
Department Of Chemistry Faculty Of Science Hirosaki University
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Kambara Tomihito
Department Of Chemistry Faculty Of Science Hokkaido University
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Ikeuchi Mayumi
Department of Chemistry, Faculty of Science, Hokkaido University
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