Synthesis of crown ether dyes.
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概要
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Crown ether dyes were synthesized in order to develop photometric reagents which are highly selective to alkali and alkaline earth metals. They contain dissociable protons attached to the chromophores of crown ether molecule. Their extraction behavior for alkali and alkaline earth metal ions as neutral complex was examined. The dyes extract potassium and alkaline earth metals, respectively. Dyes with picrylamino chromophore are effective for extractive photometric determination of potassium. A molecular design of colorimetric reagents is discussed on the basis of crown ethers.
- 公益社団法人 日本化学会の論文
著者
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Takagi Makoto
Department Of Chemical Science And Technology Faculty Of Engineering Kyushu University
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Ueno Keihei
Department Of Organic Synthesis Faculty Of Engineering Kyushu University
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Nakamura Hiroshi
Department Of Analytical Chemistry Faculty Of Pharmaceutical Sciences Science University Of Tokyo
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Yamashita Toshiro
Department of Organic Synthesis, Faculty of Engineering, Kyushu University
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