The reductive acylation of organic disulfides with aldehydes under photochemical and radical conditions.
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概要
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The irradiation of organic disulfides in aldehyde solvents resulted in the reductive fission of the S–S linkage, giving an equimolar mixture of the corresponding thiol and the thiol acylate in a good yield. The cyclic disulfides gave mono <I>S</I>-acylated dithiols. The reaction proceeded by means of the photo-initiated radical chain mechanism, and AIBN (azobisisobutyronitrile) effected the same reaction under thermal conditions.
- 公益社団法人 日本化学会の論文
著者
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MATSUDA Tsutomu
Department of Chemistry and Chemical Engineering, Faculty of Technology, Kanazawa University
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Takagi Makoto
Department Of Chemical Science And Technology Faculty Of Engineering Kyushu University
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Tazaki Masato
Department of Organic Synthesis, Faculty of Engineering, Kyushu University
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Goto Setsuo
Department of Organic Synthesis, Faculty of Engineering, Kyushu University
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