EXTRACTION RATE-CONTROLLED SEPARATION OF METAL IONS
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概要
- 論文の詳細を見る
The extraction of Co(II), Ni(II), Cu(II). Zn(II), Cd(II), and Fe(III) was studied in water - chloroform system by using 5-(4-dodecylphenylazo)-8-hydroxyquinoline (DHQ) as chelate extraction agent. Both the equilibrium-determined metal extraction and the "extraction rate-controlled" metal extraction were treated. In the latter extraction, batch-wise procedure to effect rapid mixing and rapid separation of two immiscible phases ("rapid mix - rapid separate" concept) was adopted. A comparison of the metal extraction under rate-controlled conditions with that under equilibrium indicated that the metal selectivity was reversed for the two types of approach in the extraction of Ni(II), Co(II), and Zn(II ).
- 社団法人日本分析化学会の論文
- 1983-10-05
著者
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NAKAMURA Hiroshi
Department of Analytical Chemistry, Faculty of Pharmaceutical Sciences, Science University of Tokyo
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Takagi Makoto
Department Of Organic Synthesis Faculty Of Engineering Kyushu University
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Takagi Makoto
Department Of Chemical Science And Technology Faculty Of Engineering Kyushu University
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UENO Keihei
Department of Organic Synthesis, Faculty of Engineering Kyushu University
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Nakamura Hiroshi
Department Of Organic Synthesis Faculty Of Engineering Kyushu University
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Ueno Keihei
Department Of Organic Synthesis Faculty Of Engineering Kyushu University
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SAKKA Hideo
Department of Organic Synthesis, Faculty of Engineering Kyushu University
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Sakka Hideo
Department Of Organic Synthesis Faculty Of Engineering Kyushu University
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Nakamura Hiroshi
Department Of Analytical Chemistry Faculty Of Pharmaceutical Sciences Science University Of Tokyo
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