Photochemical reductive acylation and oxidative acyl activation on phenazine and related nitrogen heterocycles.

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概要

• 論文の詳細を見る

• Irradiation of phenazine in acetaldehyde or propionaldehyde solution gave an <I>N</I>-acylated 5,10-dihydrophenazine. Acridine similarly gave 9-acyl-9,10-dihydroacridine, and 10-methylacridinium salt gave 9-acyl-10-methyl-9,10-dihydroacridine. In methanol <I>N</I>-acylated dihydro-phenazines reacted with <I>N</I>-bromosuccinimide to give phenazine and methyl car boxy lates in quantitative yield.

• 公益社団法人 日本化学会の論文

著者

• MATSUDA Tsutomu

  Department of Chemistry and Chemical Engineering, Faculty of Technology, Kanazawa University

• Takagi Makoto

  Department Of Chemical Science And Technology Faculty Of Engineering Kyushu University

• Goto Setsuo

  Department of Organic Synthesis, Faculty of Engineering, Kyushu University

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