Metal Chelates of Some β,δ-Triketone Homologues. Copper(II) Chelates of 2,6-Diacetyl-4-methylphenol, 2,2′-Dihydroxybenzophenone, 2-Acetoacetylphenol and 2-Acetyl-1,8 -dihydroxynaphthalene
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概要
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Copper(II) chelates of 2,6-diacetyl-4-methylphenol, 2,2′-dihydroxybenzophenone, 2-acetoacetylphenol and 2-acetyl-1,8-dihydroxynaphthalene were synthesized. The first and last ligands give only a mononuclear chelate of type CuL<SUB>2</SUB> respectively, whereas the second and third ones give a binuclear complex of type Cu<SUB>2</SUB>L<SUB>2</SUB> in addition to the mononuclear complex. In the cases of the latter ligands two types of complexes are interconvertible and in a solution phase there exists an equilibrium between them. Higher temperature favors a binuclear form and lower temperature another form. Structures of the complexes are assigned with spectroscopic and thermogravimetric data.
- 公益社団法人 日本化学会の論文
著者
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Taguchi Yoshio
Department Of Neurosurgery The Jikei University School Of Medicine
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Ueno Keihei
Department Of Organic Synthesis Faculty Of Engineering Kyushu University
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Kobayashi Hiroshi
Department Of Applied Physics School Of Science And Engineering Waseda University
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Taguchi Yoshio
Department of Organic Synthesis, Faculty of Engineering, Kyushu University
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Sagara Fumio
Department of Organic Synthesis, Faculty of Engineering, Kyushu University
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Taguchi Yoshio
Department of Hydrocarbon Chemistry, Faculty of Engineering Kyoto University
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