Nucleophilic substitution with phosphide anions prepared by an action of sodium dihydridobis(2-methoxyethanolato)aluminate on phosphorus compounds.
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概要
- 論文の詳細を見る
Phosphide anions, prepared by an action of sodium dihydridobis(2-methoxyethanolato)aluminate on derivatives of phosphine, phosphine oxide, or phosphorus esters, react with primary and secondary alkyl halides to produce phosphine derivatives having a newly formed phosphorus-carbon bond. The reactivity increases in the order of chloride<bromide<iodide and of secondary<primary in alkyl halide. Reaction of phosphide anion is also feasible with <I>p</I>-toluenesulfonate. Reaction of an anion of diphenylphosphine oxide seems to proceed mainly as an <I>S</I><SUB>N</SUB>2 type process.
- 公益社団法人 日本化学会の論文
著者
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Yamashita Mitsuji
Department Of Applied Chemistry Faculty Of Engeneering Shizuoka University
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Oshikawa Tatsuo
Department Of Applied Chemistry Faculty Of Engeneering Shizuoka University
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Inokawa Saburo
Department of Chemistry Faculty of Science Kyoto University
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Yamada Manabu
Deparment of Applied Chemistry, Faculty of Engineering, Shizuoka University
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Soeda Yukio
Deparment of Applied Chemistry, Faculty of Engineering, Shizuoka University
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Nakatani Kaname
Deparment of Applied Chemistry, Faculty of Engineering, Shizuoka University
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Yamashita Hiroaki
Deparment of Applied Chemistry, Faculty of Engineering, Shizuoka University
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Suzuki Nobuyoshi
Deparment of Applied Chemistry, Faculty of Engineering, Shizuoka University
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Yamashita Mitsuji
Deparment of Applied Chemistry, Faculty of Engineering, Shizuoka University
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