The Conversion of Some Alkylxanthates to the Corresponding Trithiocarbonates. The Nucleophilic Reaction of <SUP>−</SUP>SCSSR
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概要
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The reaction of <I>O</I>-methyl-, ethyl-, and benzylxanthates with a catalytic amount of triethylamine in the presence of excess carbon disulfide gave the corresponding trithiocarbonate in good yields. The products were formed by the nucleophilic reaction of <SUP>−</SUP>SCSSR with xanthates. The kinetic study showed the following order of nucleophilicity toward xanthates in DMF:<BR><SUP>−</SUP>SCOSMe><SUP>−</SUP>SCSSMe>Me<SUB>3</SUB>N
- 公益社団法人 日本化学会の論文
著者
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Yoshida Hiroshi
Departmen Of Radiology School Of Medicine Asahikawa Medical University
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Inokawa Saburo
Department of Chemistry Faculty of Science Kyoto University
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Ogata Tsuyoshi
Department of Applied Chemistry, Faculty of Engineering, Shizuoka University
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