X-Ray Diffraction Study of Mixing States in the Carbon Tetrachloride Solutions of Methanol and Pentane
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概要
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A simple method has been proposed for estimating the state of mixing in a binary solution directly from the radial distribution function. The method has been applied to the estimation of the size of the cluster or aggregate in a binary solution of methanol and carbon tetrachloride. Pure liquid carbon tetrachloride and a binary solution of pentane and carbon tetrachloride have also been studied as reference systems. The number of methanol molecules which form a cluster in the solution at the volume ratio of 8.5(CCl<SUB>4</SUB>):1.5(CH<SUB>3</SUB>OH) has been estimated to be about 18, which is in good agreement with an estimate by light scattering.
- 日本化学会の論文
著者
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Tohji Kazuyuki
Department Of Chemistry Faculty Of Science Gakushuin University
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Nishikawa Keiko
Department Of Biology Faculty Of Science Ochanomizu University
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Tanaka Masami
Department Of Applied Chemistry College Of Engineering University Of Osaka Prefecture
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Tohji Kazuyuki
Department of Chemistry, Faculty of Science, Gakushuin University
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Fujiyama Tsunetake
Institute for Molecular Science
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Nishikawa Keiko
Department of Chemistry, Faculty of Science, Gakushuin University
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Tanaka Masami
Department of Chemistry, Faculty of Science, Tokyo Metropolitan University
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