Fluctuation of local field and depolarization degree of the .UPSILON.1 line of carbon tetrachloride.
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概要
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The depolarization degree of a molecule having a T<SUB>d</SUB> symmetry was expressed in terms of the mean square fluctuation of the local field which is felt by a molecule in the condensed phase. By the use of the mean square amplitude values observed by the X-ray diffraction method, the depolarization degree of liquid carbon tetrachloride was calculated to be 0.0021, which agrees well with the observed value of 0.0039±0.0002.
- 公益社団法人 日本化学会の論文
著者
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Fujiyama Tsunetake
Institute for Molecular Science
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Hyodo Shi-aki
Department of Chemistry, Faculty of Science, Tokyo Metropolitan University
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