Shapes of the .UPSILON.1 band of liquid chloroform and intermolecular interaction.
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概要
- 論文の詳細を見る
The infrared absorption spectrum for the ν<SUB>1</SUB> fundamental of chloroform or chloroform-<I>d</I> shows strong asymmetry, with a remarkable tailing on the high-frequency side. The observed band-width of the ν<SUB>1</SUB> fundamental of chloroform-<I>d</I> is significantly narrower than that of chloroform. These asymmetric band profiles of the ν<SUB>1</SUB> bands of chloroform and chloroform-<I>d</I> can be interpreted in terms of the existence of two different types of chloroform molecules. One is a molecule which interacts with another molecule, and the other is a non-interacting molecule. The isotope effect on the band-width can be explained in terms of the difference in the reduced mass for chloroform and chloroform-<I>d</I>.
- 公益社団法人 日本化学会の論文
著者
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Suzuki Tetsuo
Department Of Chemical Engineering Kyoto University
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Fujiyama Tsunetake
Institute for Molecular Science
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Tsutsui Yumiko
Department of Chemistry, Faculty of Science, Tokyo Metropolitan University
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