Shapes of the .UPSILON.1 band of liquid chloroform and intermolecular interaction.

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概要

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• The infrared absorption spectrum for the ν<SUB>1</SUB> fundamental of chloroform or chloroform-<I>d</I> shows strong asymmetry, with a remarkable tailing on the high-frequency side. The observed band-width of the ν<SUB>1</SUB> fundamental of chloroform-<I>d</I> is significantly narrower than that of chloroform. These asymmetric band profiles of the ν<SUB>1</SUB> bands of chloroform and chloroform-<I>d</I> can be interpreted in terms of the existence of two different types of chloroform molecules. One is a molecule which interacts with another molecule, and the other is a non-interacting molecule. The isotope effect on the band-width can be explained in terms of the difference in the reduced mass for chloroform and chloroform-<I>d</I>.

• 公益社団法人 日本化学会の論文

著者

• Suzuki Tetsuo

  Department Of Chemical Engineering Kyoto University

• Fujiyama Tsunetake

  Institute for Molecular Science

• Tsutsui Yumiko

  Department of Chemistry, Faculty of Science, Tokyo Metropolitan University

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