Spectroscopic study of concentration fluctuation and intermolecular interaction in liquid.
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概要
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The band widths of the infrared absorption spectra were observed for binary solutions of methyl iodide, methyl cyanide, chloroform, and carbon disulfide. The observed bands are: the <I>v</I><SUB>1</SUB> fundamental of chloroform in carbon disulfide and in carbon tetrachloride; the <I>v</I><SUB>2</SUB> fundamental of methyl iodide in methyl cyanide, nitromethane, benzene, carbon disulfide, and carbon tetrachloride; the 2<I>v</I><SUB>2</SUB> band of methyl iodide in methyl cyanide, and the <I>v</I><SUB>8</SUB> and 2<I>v</I><SUB>8</SUB> bands of methyl cyanide in methyl iodide. The concentration dependence of a band width was explained in terms of the concentration fluctuation. The theory was compared with the observed band widths, together with the light-scattering data. A fluctuation volume was related with the intermolecular interactions in these binary solutions.
- 公益社団法人 日本化学会の論文
著者
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Suzuki Tetsuo
Department Of Chemical Engineering Kyoto University
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Fujiyama Tsunetake
Department of Chemistry, Faculty of Science, Tokyo Metropolitan University
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Suzuki Tetsuo
Department of Chemistry, Faculty of Science, Tokyo Metropolitan University
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Kakimoto Masao
Department of Chemistry, Faculty of Science, The University of Tokyo
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