Calculation of the Widths for Isotropic Parts of Highly-polarized Raman Lines: Vibrational Relaxation of Infrared-inactive Levels
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概要
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A theoretical calculation is made to explain the widths of the isotropic parts of polarized Raman lines in liquids. The calculation is based on the model of the intermolecular resonance-type vibrational relaxation through the vibration-dependent term of the Lennard-Jones atom-atom interaction. The result is applied to the Raman lines of liquid nitrogen, oxygen, and carbon disulfide, and compared with the experimental data.
- 公益社団法人 日本化学会の論文
著者
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Kakimoto Masao
Department of Chemistry, Faculty of Science, The University of Tokyo
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Fujiyama Tsunetake
Department of Chemistry, Faculty of Science, The University af Tokyo
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