Vibration Spectra and Molecular Structures of <I>n</I>-Butyl Chloride and <I>n</I>-Butyl Bromide in Relation to Parallel (1:3) Interactions

スポンサーリンク

概要

• 論文の詳細を見る

• The vibration spectra of liquid <I>n</I>-butyl chloride and <I>n</I>-butyl bromide are observed in the region of 1500–100 cm<SUP>−1</SUP>. From the analyses of spectra corresponding to the skeletal deformation vibrations, the molecular configurations are determined for both molecules. All the possible rotational isomers, the TT, GT, TG, GG, and GG′ forms, are observed for <I>n</I>-butyl chloride, while four isomers, the TT, GT, TG, and GG forms, are observed for <I>n</I>-butyl bromide. The results are compared with those of the electron-diffraction methods. It is shown that unfamiliar interactions must be considered for the parallel (1:3) interaction between methyl and chlorine substituents.

• 公益社団法人 日本化学会の論文

著者

• Fujiyama Tsunetake

  Department of Chemistry, Faculty of Science, The University af Tokyo

関連論文

• Vibration-Rotation Spectrum of Methyl Fluoride. I. Analysis of 2ν3 Band
• Measurement and analysis of the .UPSILON.3 band of CF4.
• Temperature effects on the Raman intensity of liquid samples and an averaged molecular field.
• The Polarization Measurement of He-Ne Laser Excitation Raman Lines of Liquid Acetone
• The concentration dependence of the Raman intensity in binary mixtures and the determination of polarizability and hyperpolarizability derivative tensors.
• Analysis of Skeletal Deformation Vibration Spectra in Relation to the Molecular Structure
• Associated complex formation in a binary solution and the concentration fluctuation: The chloroform-diethyl ether system.
• Vibration Spectra and Molecular Structures of n-Butyl Chloride and n-Butyl Bromide in Relation to Parallel (1:3) Interactions
• Concentration fluctuation and the light-scattering spectrum.
• Trans-Gauche Equilibrium of 1,2-Dibromoethane and Dipole-interactions in Solutions
• Vibration-Rotation Spectrum of Methyl Fluoride II. Analysis of ν3+ν6 Band
• A high-resolution vacuum spectrometer for the infrared.
• Calculation of the Widths for Isotropic Parts of Highly-polarized Raman Lines: Vibrational Relaxation of Infrared-inactive Levels
• Light scattering study of local structures in solutions. Structure-forming effect of non-associative solvent on ethanol aggregate.
• Absorption Band Shapes and Molecular Reorientation of Liquid Methyl Cyanide
• Shapes of Fundamental Bands of Liquid Carbon Disulfide, Vibrational and Reorientational Relaxations

もっと見る 閉じる

スポンサーリンク