Temperature effects on the Raman intensity of liquid samples and an averaged molecular field.
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概要
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The relative Raman intensities of the <I>v</I><SUB>1</SUB> line of carbon tetrachloride, the <I>v</I><SUB>8</SUB> line of acetonitrile, and the <I>v</I><SUB>3</SUB> line of chloroform were observed in the liquid phase and at various temperatures. The apparent intensity change due to the temperature were explained in terms of the local field effect, the density change, the statistical distribution effect, and the contribution of transition hyperpolarizability in the presence of a non-zero averaged molecular field.
- 公益社団法人 日本化学会の論文
著者
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Hatakeyama Haruo
Department of Chemistry, Faculty of Science, Tokyo Metropolitan University
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Fujiyama Tsunetake
Department of Chemistry, Faculty of Science, The University af Tokyo
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