The concentration dependence of the Raman intensity in binary mixtures and the determination of polarizability and hyperpolarizability derivative tensors.
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概要
- 論文の詳細を見る
Raman intensities were observed at various concentrations. The observed lines were: the ν<SUB>8</SUB> line of CH<SUB>3</SUB>CN (in CCl<SUB>4</SUB> and CH<SUB>3</SUB>I), the ν<SUB>3</SUB> line of CH<SUB>3</SUB>I (in CCl<SUB>4</SUB>), and the ν<SUB>2</SUB> line of CHCl<SUB>3</SUB> (in CCl<SUB>4</SUB>). Even after the elimination of the local-field effect, the Raman intensities showed concentration dependencies. The observed solvent effects were explained quantitatively by the use of the dipole interaction model. The polarizability and hyperpolarizability derivatives were determined for the ν<SUB>8</SUB> fundamental of CH<SUB>3</SUB>CN. The criteria for the internal standard method were discussed quantitatively.
- 公益社団法人 日本化学会の論文
著者
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Koike Jun
Department Of Cardiology Surugadai Nihon University Hospital
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Suzuki Tetsuo
Department Of Chemical Engineering Kyoto University
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Fujiyama Tsunetake
Department of Chemistry, Faculty of Science, The University af Tokyo
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Koike Jun
Department of Chemistry, Faculty of Science, Tokyo Metropolitan University
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