Preparation and structures of acetylene adducts of 4,6-O-isopropylidene-and 4-O-acetyl-6-O-triphenylmethyl-1,5-anhydro-2-deoxy-D-erythro-hex-1-en-3-uloses.
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概要
- 論文の詳細を見る
Cyclobutene adducts were formed stereoselectively in good yields by the irradiation of acetone solutions of 4,6-<I>O</I>-isopropylidene- and 4-<I>O</I>-acetyl-6-<I>O</I>-triphenylmethyl-1,5-anhydro-2-deoxy-D-<I>erythro</I>-hex-1-en-3-uloses, derived from D-glucal triacetate, in the presence of acetylene. The stereochemistry at the ring junction was achieved by a single-crystal X-ray analysis and a chemical correlation with the derived compounds.
- 公益社団法人 日本化学会の論文
著者
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Matsui Takanao
Faculty Of Engineering Miyazaki University
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Nakayama Mitsuru
Department Of Agricultural Chemistry College Of Agriculture University Of Osaka Prefecture
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Morooka Takashi
Faculty of Engineering, Miyazaki University
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