Electronic structure of (BEDT-TTF)CuCl2 complex.
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概要
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The X-ray photoelectron spectra and the ESR spectra of the (BEDT–TTF)CuCl<SUB>2</SUB> complex were taken. The analysis of the X-ray photoelectron spectra shows that the Cu atoms in (BEDT–TTF)CuCl<SUB>2</SUB> are in a mixed-valence state consisting of mono and bivalent cations and the concentration ratio of Cu(I) and Cu(II) is determined to be 2:1. The ESR signals show the presence of the BEDT–TTF cation radical and Cu(II)Cl<SUB>2</SUB>. The temperature dependence of the magnetic susceptibility of these components were obtained from the ESR data.
- 公益社団法人 日本化学会の論文
著者
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Inokuchi Hiroo
Institute For Molecular Science
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Tanaka Jiro
Department Of Biomaterials Okayama University Graduate School Of Medicine Dentistry And Pharmaceutic
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Enoki Toshiaki
Institute For Molecular Science
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Sano Mitsuru
Department Of Chemistry College Of General Education Nagoya University
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TANAKA Masashi
Department of Biology, Faculty of Science, Tokyo Metropolitan University
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Kawamoto Atsushi
Department of Biology, Faculty of Science, Chiba University
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Sano Mitsuru
Department of Applied Chemistry, Faculty of Engineering, University of Osaka Prefecture
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