Electronic structure of (BEDT-TTF)CuCl2 complex.

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概要

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• The X-ray photoelectron spectra and the ESR spectra of the (BEDT–TTF)CuCl<SUB>2</SUB> complex were taken. The analysis of the X-ray photoelectron spectra shows that the Cu atoms in (BEDT–TTF)CuCl<SUB>2</SUB> are in a mixed-valence state consisting of mono and bivalent cations and the concentration ratio of Cu(I) and Cu(II) is determined to be 2:1. The ESR signals show the presence of the BEDT–TTF cation radical and Cu(II)Cl<SUB>2</SUB>. The temperature dependence of the magnetic susceptibility of these components were obtained from the ESR data.

• 公益社団法人 日本化学会の論文

著者

• Inokuchi Hiroo

  Institute For Molecular Science

• Tanaka Jiro

  Department Of Biomaterials Okayama University Graduate School Of Medicine Dentistry And Pharmaceutic

• Enoki Toshiaki

  Institute For Molecular Science

• Sano Mitsuru

  Department Of Chemistry College Of General Education Nagoya University

• TANAKA Masashi

  Department of Biology, Faculty of Science, Tokyo Metropolitan University

• Kawamoto Atsushi

  Department of Biology, Faculty of Science, Chiba University

• Sano Mitsuru

  Department of Applied Chemistry, Faculty of Engineering, University of Osaka Prefecture

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