Thermal cis-trans isomerization of (CH)x and (CD)x.
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概要
- 論文の詳細を見る
Thermal <I>cis</I>-<I>trans</I> isomerization of poly(acetylene), (CH)<I><SUB>x</SUB></I>, and poly(acetylene-<I>d</I><SUB>2</SUB>), (CD)<I><SUB>x</SUB></I>, is investigated by visible spectroscopy over the temperature range 90–150 °C. The reaction does not obey simple kinetics. The initial time activation energy for the <I>cis</I>-<I>trans</I> isomerization is 11 kcal/mol for (CH)<I><SUB>x</SUB></I> and 16 kcal/mol for (CD)<I><SUB>x</SUB></I>.
- 公益社団法人 日本化学会の論文
著者
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Yasuda Hajime
Department Of Applied Chemistry Faculty Of Engineering Hiroshima University
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Tanaka Jiro
Department Of Biomaterials Okayama University Graduate School Of Medicine Dentistry And Pharmaceutic
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TANAKA Masashi
Department of Biology, Faculty of Science, Tokyo Metropolitan University
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Yasuda Hajime
Department of Chemistry, Faculty of Science, Nagoya University
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