Electronic structures of 3,4:3',4'-bis(tetramethylene)-2,2',5,5'-tetrathiafulvalene-TCNQ and 3,4:3',4'-bis(tetramethylene)-2,2',5,5'-tetrathiafulvalene-1,4-dihydro-1,4-bis(dicyanomethylene)triptycene complex crystals.
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概要
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Experimental results of the polarized reflection spectra and the calculated absorption spectra of 3,4:3′,4′-bis(tetramethylene)-2,2′,5,5′-tetrathiafulvalene (OMTTF)–TCNQ and OMTTF–1,4-dihydro-1,4-bis(dicyanomethylene)triptycene(DBTCNQ) crystals are discussed by developing approximate theoretical models, based on the CT mechanism. The electronic structures conform well that, OMTTF–TCNQ is a neutral crystal whereas, OMTTF–DBTCNQ is ionic. Furthermore, the temperature dependent spin susceptibilities imply the former as diamagnetic and the latter as a regular Heisenberg antiferromagnet.
- 公益社団法人 日本化学会の論文
著者
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Murata Ichiro
Department Of Cardiovascular Medicine Graduate School Of Medicine
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Tanaka Jiro
Department Of Biomaterials Okayama University Graduate School Of Medicine Dentistry And Pharmaceutic
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Nakasuji Kazuhiro
Department Of Chemistry Graduate School Of Science Osaka University
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Akhtar Shamim
Department of Chemistry, Faculty of Science, Nagoya University
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