Conformational adaptation: A new aspect of substitutent effects.
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概要
- 論文の詳細を見る
Methoxyl (CH<SUB>3</SUB>O–) substituent on unsaturated molecules was suggested by ab initio molecular orbital calculation and qualitative orbital interaction theory to change from coplanar to vertical conformation on electron acceptance. The conformational adaptation can make it possible that methoxyl group is less electron-donating than methyl group.
- 公益社団法人 日本化学会の論文
著者
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Murata Ichiro
Department Of Cardiovascular Medicine Graduate School Of Medicine
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Yamamura Kimiaki
Department Of Chemistry College Of General Education Kobe University
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Nakasuji Kazuhiro
Department Of Chemistry Graduate School Of Science Osaka University
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Miyake Hideyoshi
Department Of Agrobioscience Graduate School Of Agricultural Science Kobe University
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Inagaki Satoshi
Department Of Chemistry Faculty Of Engineering Gifu University
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Okajima Takehiko
Department of Chemistry, Faculty of Engineering, Gifu University
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