A convenient synthesis of (2R)-1-amino-1-deoxy-1-phosphinylglycerols.
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概要
- 論文の詳細を見る
2,3-<I>O</I>-Isopropylidene-D-glyceraldehyde reacts with dimethylphosphine oxide in the presence of triethylamine to give separable (1<I>S</I>,2<I>R</I>)-and (1<I>R</I>,2<I>R</I>)-1-dimethylphosphinylgrycerol (65 :35), from which the (1<I>R</I>) and (1<I>S</I>) title compounds are respectively derived via 1-<I>O</I>-mesyl and 1-azido derivatives. The corresponding 1-dimethoxyphosphinylglycerols are similarly prepared. Structural and conformational assignments of these products are made on the basis of the <SUP>1</SUP>H NMR data and [α]<SUB>D</SUB> values.
- 公益社団法人 日本化学会の論文
著者
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Hanaya Tadashi
Department Of Chemistry Faculty Of Science Okayama University
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Yamamoto Hiroshi
Departmemt Of Chemical Engineering University Of Tokyo
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Kawamoto Heizan
Department Of Chemistry Faculty Of Science Okayama University
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Hogg Alan
Department of Chemistry, University of Alberta
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Armour Margaret-Ann
Department of Chemistry, University of Alberta
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Noguchi Ayashi
Department of Chemistry, Faculty of Science, Okayama University
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Miyoshi Akihiko
Department of Chemistry, Faculty of Science, Okayama University
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