Intramolecular Hydrogen Bonds. XVII. Intramolecular Hydrogen Bonding Involving the Mercapto Group as a Hydrogen Donor

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概要

• 論文の詳細を見る

• The SH stretching absorption spectra of some mercapto compounds in dilute carbon tetrachloride solutions and also in acetonitrile solutions have been measured at 20°C. Alkyl mercaptans show absorption bands which are suggestive of the rotational isomerism around the C–S bond. The spectral data indicate that benzyl mercaptan, ω-ethoxyalkyl mercaptans, and ethyl α- and β-mercaptoalkanoates form practically no intramolecular hydrogen bond between the SH group and the hydrogen-acceptor group. In thiosalicylic acid and its ethyl ester, the hydrogen-bonding to the carbonyl group is partially possible even in acetonitrile. On the other hand, the corresponding free carboxylic acids are not hydrogen-bonded between the S atom and the carboxyl group.

• 公益社団法人 日本化学会の論文

著者

• Suzuki Koichi

  Department Of Agro-bioscience Faculty Of Agriculture Iwate University

• Nakamura Mikio

  Department Of Anatomy Jikei-kai School Of Medicine

• Mori Nobuo

  Department of Chemistry Tokyo College of Science

• Tsuzuki Yojiro

  Department of Chemistry, Science University of Tokyo

• Kaido Shinichi

  Department of Chemistry, Science University of Tokyo

• Nakamura Mikio

  Department of Chemistry, Science University of Tokyo

• Suzuki Koichi

  Department of Chemistry, Science University of Tokyo

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