The Cd 5 <SUP>3</SUP>P<SUB>0</SUB> State in the Cadmium-photosensitized Reaction and the Quenching of the Resonance Radiation at 326.1 nm by Nitrogen, Carbon Monoxide, and Carbon Dioxide

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概要

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• The emission of the resonance line at 326.1 nm (5 <SUP>3</SUP>P<SUB>1</SUB>→5 <SUP>1</SUP>S<SUB>0</SUB>) and the absorptions of Cd(<SUP>3</SUP>P<SUB>0</SUB>) at 340.4 nm (5 <SUP>3</SUP>D<SUB>1</SUB>←5 <SUP>3</SUP>P<SUB>0</SUB>) and of Cd(<SUP>3</SUP>P<SUB>1</SUB>) at 346.6 nm (5 <SUP>3</SUP>D<SUB>2</SUB>←5 <SUP>3</SUP>P<SUB>1</SUB>) have been measured as functions of the pressure of foreign gases at 250°C. At the pressures higher than 1 Torr of any rare gas, an equilibrium was established between 5 <SUP>3</SUP>P<SUB>1</SUB> and 5 <SUP>3</SUP>P<SUB>0</SUB> states. The efficiency of nitrogen in producing the 5 <SUP>3</SUP>P<SUB>0</SUB> state from the 5 <SUP>3</SUP>P<SUB>1</SUB> state was found to be more than 10<SUP>3</SUP> times those of rare gases. The quenching efficiencies of nitrogen, carbon monoxide, and carbon dioxide for the resonance radiation at 326.1 nm were also measured by using argon as the diluent gas. The halfquenching pressures obtained were 73±3, 0.47±0.01, and 0.096±0.003 Torr for nitrogen, carbon monoxide, and carbon dioxide respectively.

• 公益社団法人 日本化学会の論文

著者

• Yamamoto Shunzo

  Department Of Chemistry Faculty Of Science Okayama University

• Tsunashima Shigeru

  Department of Applied Physics, Tokyo Institute of Technology

• Sato Shin

  Department of Applied Physics, Tokyo Institute of Technology

• Takaoka Motoaki

  Department of Applied Physics, Tokyo Institute of Technology

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