The Insertion Reaction of NH Singlet Radicals into the C–H Bonds of Cyclopropane and Isobutane in the Liquid Phase

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概要

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• Hydrogen azide was photolyzed in liquid cyclopropane at the temperature of Dry Ice–methanol. The main products observed were nitrogen, cyclopropylamine, and ammonia. The relative yields of the products depended slightly on the concentration of hydrogen azide. The results were then compared with those obtained with paraffin and olefin. The isobutane solution of hydrogen azide was photolyzed at 0 °C. The products observed were the same as those obtained at the temperature of Dry Ice-methanol. The relative yields of the products and the concentration dependence, however, were different.

• 公益社団法人 日本化学会の論文

著者

• Tsunashima Shigeru

  Department of Applied Physics, Tokyo Institute of Technology

• Sato Shin

  Department of Applied Physics, Tokyo Institute of Technology

• Hamada Jun-ich

  Department of Applied Physics, Tokyo Institute of Technology

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