The Liquid-phase γ-Radiolysis of Benzene-Nitrous Oxide Mixtures

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概要

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• The γ-radiolysis of the benzene-nitrous oxide liquid mixtures has been studied at room temperature and at 0°C, the mixing ratios covering almost all the range from pure benzene to pure nitrous oxide. Phenol was found to be one of the main products; its <I>G</I>-value is about a half of that of nitrogen at the lower concentration of nitrous oxide. Kinetic analysis shows that the <I>G</I>-values of electrons from benzene are 3.2±0.2. An empirical equation for expressing the <I>G</I>-value of nitrogen from the benzene solution of nitrous oxide proposed by Hentz and Sherman (<I>J. Phys. Chem.</I>, <B>73</B>, 2676 (1969).) was examined. The agreement was very poor at higher concentrations of nitrous oxide. Possible reasons were discussed.

• 公益社団法人 日本化学会の論文

著者

• Shishido Seishi

  Department of Applied Physics, Tokyo Institute of Technology

• Hirokami Shun-ichi

  Department of Applied Physics, Tokyo Institute of Technology

• Sato Shin

  Department of Applied Physics, Tokyo Institute of Technology

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