The reactions of NH radicals with ethylene and propene in the liquid phase.

スポンサーリンク

概要

• 論文の詳細を見る

• The photolysis of hydrogen azide was studied in liquid ethylene, propene, and the mixture with ethane at the temperature of Dry Ice–methanol. The products observed were aziridine (0.18), ammonia (0.16), and nitrogen (1.0) from the ethylene solution and 2-methylaziridine (0.33), allylamine (0.12), ammonia (0.17), and nitrogen (1.0) from the propene solution. The values in parentheses show the yields relative to that of nitrogen. The relative yields were independent of the concentration of hydrogen azide in the range of 0.8–8×10<SUP>−2</SUP> mol dm<SUP>−3</SUP>. The reaction of NH(a<SUP>1</SUP>Δ) radicals with olefin consists of three processes: the addition to double bond, the insertion into the C–H bond, and the deactivation to the <SUP>3</SUP>Σ<SUP>−</SUP> state. The branching ratios and the relative rate constants of the reactions of NH(a<SUP>1</SUP>Δ) radicals with ethylene, propene, and ethane were estimated.

• 公益社団法人 日本化学会の論文

著者

• Kitamura Takashi

  Department Of Biology Graduate School Of Science Kyushu University

• Tsunashima Shigeru

  Department of Applied Physics, Tokyo Institute of Technology

• Sato Shin

  Department of Applied Physics, Tokyo Institute of Technology

• Kitamura Takashi

  Department of Applied Physics, Tokyo Institute of Technology

関連論文

• Visible Nonlinear Band-Edge Luminescence in ZnSe and CdS Excited by a Mid-Infrared Free-Electron Laser
• Influences of Ga ion Irradiation on Magnetic Properties of Planar-patterned Co/Pd multilayers
• Magnetic Domain Structure of NiFe and MnIr/NiFe Elelnents Patterned by Focused Ion Beam
• Properties of Amorphous Iron-Metalloid Thin Films
• Magnetic and Magnetoelastic Properties of Amorphous Fe-Si Films
• Magnetization Process of Exchange-Coupled Ferrimagnetic Double-Layered Films
• Magnetic After-Effect in Amorphous Tb-Fe Thin Films
• Giant Magnetoresistance in FeNiCo/Cu Multilayers
• Giant Magnetoresistance Effect in CoFeB/Cu/CoFeB Spin Valves
• Magnetoresistance Effects in Ni-Fe-Co/Cu/Co-Pt Trilayers
• Magnetostriction and Perpendicular Magnetic Anisotropy of Amorphous GdFeCo Thin Films : Magnetism, Magnetic Materials Devices
• Perpendicular Magnetic Anisotropy of TbCo Films
• Measurement of Magnetostriction of Amorphous Dy-Fe Films by Cantilever Capacitance Method
• Magnetostriction of Amorphous Gd-Fe and Tb-Fe Sputtered Films
• Magnetic Torque in Gd-Co Film with Layer Structure
• Thickness Dependence of Magnetic Annealing Behavior in Permalloy Films
• Annealing Behavior of As-Deposited Permalloy Films
• Relaxation Process of M-Induced Uniaxaial Magnetic Anisotropy
• Structure and Soft Magnetic Properties of Fe/CoZr Multilayer Films
• Kerr Rotation of Quenched High-Temperature-Phase MnBi Film
• Measurement of Magnetostriction Constants in (111)-Oriented Polycrystalline PdCo Alloy and Multilayered Films
• Magneto-Optical Kerr Spectra of Ultrathin Co Films
• Observation of Thermomagnetically Recorded Magnetic Domains in TbFeCo Films With Soft X-Ray Microscopy : Magnetism
• CALMODULIN IN THE CILIARY CONTROL OF PARAMECIUM CAUDATUM(Cell Biology and Morphology,Abstracts of papers presented at the 74^ Annual Meeting of the Zoological Society of Japan)
• A Case of Congenital Infantile Fibrosarcoma of the Right Hand
• Cosmic Rays Intensities under Sea-Water at Depths down to 1,500 Meters
• Luminescence of Pyrene-Doped Amorphous Silica Glasses Prepared by the Sol-Gel Method
• Microstructures of Pt/Co Films Deposited on Sputter-Etched Underlayers
• Control of the Exchange-Coupling Force in Magnetic Super Resolution Magnetooptical Recording Media with In-Plane Magnetization Layers
• Anisotropic Magnetoresistance of Amorphous Fe-Zr Alloy Films
• Magnetic Anisotropy and Magneto-Optic Kerr Spectra of Amorphous Ho-Co Thin Films
• A case of hepatic pseudolymphoma observed without surgical intervention
• LAPAROSCOPIC ABLATION THERAPY FOR HEPATOCELLULAR CARCINOMA
• Bi系酸化物超伝導体のT_cに及ぼすLi添加の影響
• A Proposal of the Method for Energy Measurements of Muons over 10 TeV
• On the Study of the Penetrating Burst at High Altitude
• ENDOSCOPIC TREATMENT OF MUCOSAL DIAPHRAGM WITH ENTEROLITH IN THE JEJUNUM OF AN ADULT
• Special Issue on High Density Information Recording Technologies
• Effect of Preparation Conditions of Titanium Oxide on Dinitrogen Fixation to Ammonium Salt
• Running wheel exercises accelerate neuronal turnover in mouse dentate gyrus
• Dynamic Heating in Micron- and Submicron-Patterned TbFe Films
• Magnetic Force Microscopy Study of Thermomagnetic Writing on Micron- and Submicron-Patterned TbFe Films Using Current Pulses
• Effect of Sputtering Deposition Process on Magnetic Properties of Magnetic Multilayers
• The Benzene-photosensitized Decomposition of Carbonyl Sulfide in a Cyclohexane Solution
• COS as an Electron Scavenger in Liquid-phase Radiolysis
• Cisplatin-Induced Rat Renal Interstitial Fibrosis ; A Possible Pathogenesis Based on the Data
• Anomalous Interactions of High Energy Muons
• Kinetic isotope effects in the H+C3H6.RAR.C3H7 reaction.
• Dependences of Giant Magnetoresistance in Co/Cu Multilayers on Sputtering Conditions
• Structural and Magnetic Anisotropy of Tb/Fe Multilayers
• Photoinduced Processes of Solid Aromatic Compounds by Mid-IR Free Electron Laser
• Temperature dependence of the rate constants of H and D-atom additions to C2H4,C2H3D,C2D4,C2H2,and C2D2.
• Absolute rate constants for the reactions of O(3P) with several molecules.
• The rate constants for H and D-atom additions to O2, NO, acetylene, and 1,3-butadiene.
• The Quenching of the Cadmium Resonance Radiation at 326.1 nm by Ammonia and the Emission from the Complex between Excited Cadmium Atoms and Ammonia in the Presence of Argon
• The Basic Compound Produced in the γ-Radiolysis of Liquid Nitrogen Containing Hydrocarbons
• The Photolysis of Cyclopentanone
• The Cadmium-photosensitized Decomposition of Acetone
• The Spatial Distribution of Secondary Electrons Produced in the γ-Radiolysis of Cyclohexane
• Methane Formation in the Radiolysis of Neopentane and Isooctane
• Arrhenius parameters for the reactions of hydrogen and deuterium atoms with four butenes.
• The reactions of NH(a1.DELTA.) with ethane, propane, and isobutane in the liquid phase.
• The reactions of hydrogen and deuterium atoms with four ketenes.
• The relative rate constants of reactions of oxygen atoms with several olefins in liquid carbon dioxide.
• The reactions of the singlet NH radicals with C4 olefins in the liquid phase.
• The precursors of phenols produced in the .GAMMA.-radiolysis of aromatic hydrocarbons in liquid carbon dioxide.
• The Estimation of the G-Values for the Ionization and Excitation of Noble Gases Irradiated by 100 keV Electrons
• The reactions of singlet NH radicals with methyl and ethyl alcohols in the liquid phase.
• The estimation of the G-values for ionization and excitation of ten-electron molecules: Methane, ammonia, and water irradiated bkeV keV electrons.
• The formation of amino acids by the reactions of singlet NH with several carboxylic acids.
• The reactions of NH radicals with ethylene and propene in the liquid phase.
• The .GAMMA.-ray induced oxidation of aromatic hydrocarbons in liquid dinitrogen oxide.
• Emission Processes in Cadmium Photosensitization
• A comparison of the primary processes of the radiolyses induced by .ALPHA.-,.BETA.-,and .GAMMA.-rays.
• Degradation spectra and the G-values for ionization and excitation of the mixtures of noble gases.
• The .GAMMA.-ray induced oxidation of cyclohexene in the liquid dinitrogen oxide at -18.DEG.C.
• The formation of nitrogeneous compounds in the .GAMMA.-radiolyses of liquid nitrogen solutions of hydrogen, methane, and ethane.
• The Quenching of the Cadmium Resonance Radiation at 326.1 nm by Some Aliphatic Amines and the Cadmium-sensitized Luminescence of These Amines
• The spatial distribution of secondary electrons produced in the .GAMMA.-radiolysis of water.
• Energy Transfer in the γ-Irradiated Benzene Solutions of Carbonyl Sulfide, Nitrous Oxide, and Carbon Dioxide
• The Insertion Reaction of NH Singlet Radicals into the C–H Bonds of Cyclopropane and Isobutane in the Liquid Phase
• The application of the spin trap, phenyl t-butyl nitrone, to the study of the .GAMMA.-radiolysis of cyclohexane.
• The γ-Radiolysis of Liquid Nitrogen Containing Methane
• The reaction of N(24S3/2) with hydrogen halides and deuterium iodide.
• The 2288 Å Photolysis of Hydrogen Iodide in the Presence of Ethylene and Propylene
• The Pressure Broadening of the Cadmium-resonance Line at 326.1 nm in Ammonia and Argon
• The Calculation of the Primary Radiolysis Yield of Water Vapor Irradiated by 10-keV Electrons
• The G-value of nitrogen atoms produced in the .GAMMA.-radiolysis of liquid nitrogen and the ozone formation in the .GAMMA.-irradiated liquid nitrogen solution of oxygen.
• The Liquid-phase γ-Radiolysis of Benzene-Nitrous Oxide Mixtures
• The G-values of Nitrogen Obtained from the Gas-phase γ-Radiolysis of Nitrous Oxide–Hydrocarbon Systems
• The Reactions of Hot Deuterium Atoms with Ethylene
• Non-empirical Calculation of the G-Values for the Ionization and Excitations in Diatomic Molecules Irradiated by 100 keV Electrons
• The Contribution of the Double Collision Occurring in an Atom to the Yield of the Ionization and Excitations of Noble Gases Irradiated by 100 keV Electrons
• The isotope effect on the quenching of the cadmium triplet state by methanol.
• The Photobleaching: of Trapped Electrons and the Electron Capture of Radicals in γ-Irradiated Hydrocarbon Matrices at 77 K
• The Arrhenius parameters for the reactions of O atoms with ethene and five fluoroethenes.
• The theoretical estimation of the G-values for the ionization and excitation of thirty-eight gaseous compounds irradiated by 100 keV electrons.
• The Temperature Dependence of the G-Values of Nitrogen from the Gas-phase γ-Radiolysis of C3-Hydrocarbons in the Presence of Nitrous Oxide
• The Cd 5 3P0 State in the Cadmium-photosensitized Reaction and the Quenching of the Resonance Radiation at 326.1 nm by Nitrogen, Carbon Monoxide, and Carbon Dioxide
• The Cadmium-photosensitized Decomposition of Acetaldehyde, Propionaldehyde, and n-Butyraldehyde

もっと見る 閉じる

スポンサーリンク