The Quenching of the Cadmium Resonance Radiation at 326.1 nm by Ammonia and the Emission from the Complex between Excited Cadmium Atoms and Ammonia in the Presence of Argon

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概要

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• The pressure dependences of the emission intensities at 326.1 and 432 nm in the cadmium-photosensitized reaction of ammonia have been measured. In order to interpret the nonlinear Stern-Volmer plots for the quenching of the 326.1 nm resonance line, the following reactions have to be taken into account in the reaction scheme: Cd<SUP>*</SUP>+NH<SUB>3</SUB>\rightleftharpoonsCdNH<SUB>3</SUB><SUP>*</SUP><SUB>V</SUB>, CdNH<SUB>3</SUB><SUP>*</SUP><SUB>V</SUB>+M→CdNH<SUB>3</SUB><SUP>*</SUP>+M. The pressure dependence of the emission from the CdNH<SUB>3</SUB><SUP>*</SUP> complex (at 432 nm) was also well explained in terms of a reaction scheme involving the above reactions.

• 公益社団法人 日本化学会の論文

著者

• Yamamoto Shunzo

  Department Of Chemistry Faculty Of Science Okayama University

• Tsunashima Shigeru

  Department of Applied Physics, Tokyo Institute of Technology

• Sato Shin

  Department of Applied Physics, Tokyo Institute of Technology

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