Infrared multiple-photon decomposition of .BETA.-propiolactone.
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概要
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The infrared multiple-photon decomposition of β-propiolactone was found to give only ethylene and carbon dioxide with the same yield as the products, where the material balance was above 90%. This result suggests that the unimolecular decomposition into ethylene and carbon dioxide is a unique reaction channel of the compound at highly vibrationally excited states. It was shown that the decomposition probability was strongly dependent on the fluence but slightly dependent on the pressure.
- 公益社団法人 日本化学会の論文
著者
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Yamamoto Shunzo
Department Of Chemistry Faculty Of Science Okayama University
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ARAI Shigeyoshi
The Institute of Physical and Chemical Research
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Ishikawa Yo-ichi
The Institute of Physical and Chemical Research
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