The .GAMMA.-ray induced oxidation of cyclohexene in the liquid dinitrogen oxide at -18.DEG.C.

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概要

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• The γ-radiolysis of a cyclohexene–dinitrogen oxide mixture in the liquid phase at −18 °C has been studied and the results compared with that of the radiolysis of a cyclohexene–carbon dioxide mixture in the liquid phase.<SUP>5</SUP>) The oxidation reaction initiated by oxygen atoms produced in the direct radiolysis of dinitrogen oxide or carbon dioxide is common for both solutions, the products being cyclohexene oxide, cylohexanone, and cyclopentanecarbaldehyde. In the dinitrogen oxide solution, however, two other oxidation processes have to be considered in order to interpret the material balance of products and the formation of other oxygenated compounds: cyclohexanol, 2-cyclohexenol, and 2-cyclohexenone. A possible reaction mechanism is discussed.

• 公益社団法人 日本化学会の論文

著者

• Hirokami Shun-ichi

  Department of Applied Physics, Tokyo Institute of Technology

• Sato Shin

  Department of Applied Physics, Tokyo Institute of Technology

• Wojnarovits Laszlo

  Department of Applied Physics, Tokyo Institute of Technology

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