An Attempt to Predict Thermal Pericyclic Reactions by a Sequential Nucleophilic Scheme
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概要
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A simple, mnemonic method for predicting pericyclic reactions in ground states has been worked out by treating a multi-center reaction as a sequence of one-center reactions analogous to nucleophilic substitution type reaction. The analysis of reaction is carried out by illustrating localized MO's and their stepwise transformation. This method can lead to predictions for thermal pericyclic reactions in agreement with the Woodward-Hoffmann rules and the HOMO-LUMO interaction method. A simple modification of this method is applicable to reactions in excited states.
- 公益社団法人 日本化学会の論文
著者
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Kakehi Akikazu
Department Of Chemistry And Material Engineering Faculty Of Engineering Shinshu University
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Ito Suketaka
Department of Applied Chemistry Faculty of Engineering Nagoya University
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Tanaka Yumo
Department of Industrial Chemistry, Faculty of Engineering, Shinshu University
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