Thermal and acid-catalyzed decomposition of 3,6-diphenyl-1,4-bis-(phenylsulfonyl)-1,4-dihydro-1,2,4,5-tetrazine.
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概要
- 論文の詳細を見る
Thermolysis of the title dihydrotetrazine in boiling toluene gives benzenesulfonic anhydride, <I>S</I>-phenyl benzenethiosulfonate, and small amounts of diphenyl disulfide and a rearrangement product, 3,6-diphenyl-1,2-bis(phenylsulfonyl)-1,2-dihydro-1,2,4,5-tetrazine, together with 3,6-diphenyl-1,2,4,5-tetrazine. On the other hand, the treatment with concentrated sulfuric acid affords 3,6-diphenyl-1,4-dihydro-1,2,4,5-tetrazine in good yield. On the basis of the kinetic parameters obtained for the thermolysis, the mechanism was discussed.
- 公益社団法人 日本化学会の論文
著者
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Kakehi Akikazu
Department Of Chemistry And Material Engineering Faculty Of Engineering Shinshu University
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Ito Suketaka
Department of Applied Chemistry Faculty of Engineering Nagoya University
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Matsuno Toshiyuki
Department of Industrial Chemistry, Faculty of Engineering, Shinshu University
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Tanaka Yumo
Department of Industrial Chemistry, Faculty of Engineering, Shinshu University
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Yoshida Kazuyoshi
Department of Industrial Chemistry, Faculty of Engineering, Shinshu University
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