N-allylprazole as a ligand. III. The crystal and molecular structure of (1-allyl-3,5-dimethylpyrazole)copper(I) chloride.
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概要
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The crystal structure of (1-allyl-3,5-dimethylpyrazole) copper (I) chloride, CuCl(C<SUB>8</SUB>H<SUB>12</SUB>N<SUB>2</SUB>), has been determined by the three-dimensional X-ray analysis. The crystal is triclinic, space group P\bar1; <I>a</I>=8.442(4), <I>b</I>=8.873(6), <I>c</I>=8.112(3) Å, α=103.44(3), β=116.42(3), γ=63.37(3)° and <I>Z</I>=2. The structure was refined to an <I>R</I> value of 0.056 for 1196 collected reflections. The complex has a dimeric structure in which the copper(I) ion is surrounded quasi-tetrahedrally by two bridging chlorines, a pyrazole-nitrogen and the olefinic part of the allyl group. The C=C bond distance (1.34 Å) scarcely shows any increase upon coordination to the metal. The olefin plane is almost perpendicular to the Cu-olefin bond axis and shows no significant bendings of the olefinic atoms out of the plane.
- 公益社団法人 日本化学会の論文
著者
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Miyamoto Takeshi
Department Of Cell Differentiation Sakaguchi Laboratory Of Developmental Biology Keio University Sch
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Fukushima Kazuo
Department Of Environmental Sciences Faculty Of Science Shinshu University
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Kobayashi Akiko
Department Of Biopharmaceutics Meiji Pharmaceutical University
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Sasaki Yukiyoshi
Department of Chemistry and The Research Centre for Spectrochemistry, Faculty of Science, The University of Tokyo
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