Crystal and molecular structure of a chelating ylide complex of palladium: [(Benzoylmethylene)diphenyl-2-(diphenylphosphino)-ethylphosphorane]dichloropalladium(II) toluene solvate.
スポンサーリンク
概要
- 論文の詳細を見る
The crystal structure of the title compound was solved by single-crystal X-ray diffraction techniques. Crystals are monoclinic, space group P2<SUB>1</SUB>/<I>c</I>, with cell dimensions <I>a</I>=13.39(5), <I>b</I>=16.88(1), <I>c</I>=19.85(6) Å, β=123.54(1)°, <I>Z</I>=4. The final <I>R</I> was 0.065. The ylide ligand coordinates to palladium through the ylide carbon Pd–C, 2.115(15) Å and phosphine phosphorus Pd–P, 2.230(8) Å forming a six-membered chelate ring. The chelating ligand together with two chlorine atoms forms a square-planar geometry around the palladium. The Pd–Cl distances are discussed in terms of <I>trans</I>-influence of the ylide carbon.
- 公益社団法人 日本化学会の論文
著者
-
Kobayashi Akiko
Department Of Biopharmaceutics Meiji Pharmaceutical University
-
SAITO Taro
Department of Applied Chemistry, Graduate School of Engineering, The University of Tokyo
-
Takahashi Hirofumi
Department of Chemistry, Faculty of Science, The University of Tokyo
-
Sasaki Yukiyoshi
Department of Chemistry and The Research Centre for Spectrochemistry, Faculty of Science, The University of Tokyo
-
Oosawa Yoshinao
Department of Chemistry, Faculty of Science, The University of Tokyo
関連論文
- Mysterious Paramagnetic States of Fe 3d Spin in Antiferromagnetic Insulator of λ-BETS_2FeCl_4 System(Condensed matter: structure and mechanical and thermal properties)
- Increased Plasma Antigen Levels of Monocyte Chemo-attractant Protein-1 in Patients With Restenosis After Percutaneous Transluminal Coronary Angioplasty
- OE-209 Higher Levels of Urinary 11-dehydro-thromboxane B2 is Strongly Associated with Future Cardiovascular Events in Patients with Stable Coronary Artery Disease(OE36,Atherosclerosis (Clinical/Treatment) (IHD),Oral Presentation (English),The 73rd Annual
- FRS-037 Expression of COX-2 in Platelets is a Strong Risk Factor for Future Cardiovascular Events in Patients with Acute Coronary Syndrome(FRS8,Novel Biomarkers and Pathophysiology of ACS (IHD),Featured Research Session (English),The 73rd Annual Scientifi
- ^Se NMR Evidence for the Jaccarino-Peter Mechanism in the Field Induced Superconductor, λ-(BETS)_2FeCl_4(Condensed matter: electronic structure and electrical, magnetic, and optical properties)
- EFFECTS OF INTRACORONARY THROMBOLYSIS THERAPY IN ACUTE MYOCARDIAL INFARCTION : Ichemic Heart Disease (I) : 46th Annual Scientific Meeting, Japanese Circulation Society
- OE-247 Prospective Screening of Coronary Artery Disease in Asymptomatic Type 2 Diabetes by 64 Row Multi-Slice CT (MSCT)(OE42,CT/MRI (Coronary/Vascular) 2 (I),Oral Presentation (English),The 73rd Annual Scientific Meeting of The Japanese Circulation Societ
- New BETS Salt with Iodomercurate Anion : (BETS)_4Hg_3I_8
- -0688-DIRECT PERCUTANEOUS TRANSLUMINAL CORONARY ANGIOPLASTY COMBINED WITH INTRAVENOUS ADMINISTRATION OF RECOMBINANT TISSUE-TYPE PLASMINOGEN ACTIVATOR IN ACUTE MYOCARDIAL INFARCTION
- Crystal Structure and Physical Properties of M=Rb and Tl Salts of (BEDT-TTF)_2MM'(SCN)_4 [M'=Co, Zn]
- Single-Component Molecular Metals as Multiband π-d Systems(Condensed matter: electronic structure and electrical, magnetic, and optical properties)
- New Stable Metallic Salt Based on a Donor Molecule Containing peri-Ditellurium Bridges, TMTTeN(SCN)_
- Electronic Structures of Single Component Molecular Metals Based on Ab initio Calculation(Condensed matter: electronic structure and electric, magnetic, and optical properties)
- Resistance Measurements of Microcrystals of Single-component Molecular Metals Using Finely Patterned Interdigitated Electrodes
- INFLUENCE OF PERCUTANEOUS TRANSLUMINAL CORONARY RECANALIZATION (PTCR) ON THE RELEASE OF CREATINE PHOSPHOKINASE (CPK) : PROCEEDINGS OF THE 47th ANNUAL SCIENTIFIC MEETING OF THE JAPANESE CIRCULATION SOCIETY : Ischemic Heart Disease (III)
- THE EFFECT OF SELECTIVE INTRACORONARY THROMBOLYSIS ON THE LEFT VENTRICULAR REGIONAL WALL MOTION IN ACUTE MYOCARDIAL INFARCTION : PROCEEDINGS OF THE 47th ANNUAL SCIENTIFIC MEETING OF THE JAPANESE CIRCULATION SOCIETY : Ischemic Heart Disease (III)
- Synthesis, Structure, and Electrochemistry of a Dodecanuclear Chromium Cluster Complex 〔Cr_S_(PEt_3)_〕
- Electrical and Magnetic Properties of BETS Conductor with Modified λ-type Structure, λ'-(BETS)_2GaBr_4
- Syntheses and Crystal Structures of ET and BETS Salts Containing Bis(dithiosquarato)metalate Anions
- The Electrical Behavior of Charge-Transfer Salts Based on an Unsymmetrical Donor Bis(ethylenedithio)diselenadithiafulvalene(STF) : Disorder Effect on the Transport Properties
- Electrical Resistivity under High Pressure and Upper Critical Magnetic Field of the Molecular Superconductor α-(EDT-TTF)[Ni (dmit)_2]
- Electrical and Optical Properties of α-(BETS)_2I_3 and α-(BEDT-STF)_2I_3
- New Organic Metals Based on BETS Compounds with MX_ Anions (BETS=bis(ethylenedithio)tetraselenafulvalene; M = Ga, Fe, In; X=Cl, Br)
- New Molecular Superconductor, [Me_2Et_2N] [Pd(dmit)_2]_2
- Superconducting Transition Temperature of the Organic Alloy System. κ-[(BEDT-TTF)_(BEDT-STF)_x]_2Cu[N(CN)_2」Br
- Proteasome inhibitors induce phosphorylation of neurofilaments and activate c-Jun N-terminal kinase(JNK).
- Syntheses and Structures of Trinuclear Molybdenum Cluster Complexes [Mo_3S_4Cl_4(C_5H_5N)_5] and [Mo_3S_4Cl_3(C_5H_5N)_6]I
- Synthesis and Structure of a Pyridine Complex of Trinuclear Molybdenum Cluster [Mo_3S_4Cl_4(py)_5]
- Cu NMR Study in DCNQI-Cu System
- Diffuse Scattering from the Channel-type Composite Crystals Pb_Cr_2S_, Sr_Cr_2S_ and Ba_Cr_2Se_ (p ~ 0.3)
- Synthesis and Structure of a Trinuclear Rhenium Cluster Complex [PEt_3H][Re_3(μ_3-S)(μ-S)_3Cl_6(PEt_3)_3]
- Synthesis of Trinuclear Rhenium Halide Sulfide Cluster Complexes with Triethylphosphine Ligands [Re_3(μ_3-S)_2(μ_2-S)_2(μ_2-Br)Br_2(PEt_3)_4]and[Re_3(μ_3-S)_2(μ_2-S)_2(μ_2-Cl)Cl_3(PEt_3)_3]
- Synthesis of a Mixed-Metal Cluster Complex of Rhenium and Nickel[Re_3NiS_4Cl_6(PEt_3)_4]
- Formate Dehydrogenase in Rice Plant : Growth Stimulation Effect of Formate in Rice Plant
- First Ambient-pressure Superconductor Based on Ni(dmit)2, α-EDT-TTF[Ni(dmit)2]
- Metal Instability of (DMe-DCNQI)_2 Cu Induced by Uniaxial Stress and Enhancement of Electron Mass
- Magnetic and Structural Properties of Mixed-Valence Molecular Conductors (DMeDCNQI)_2Cu and (DMeODCNQI)_2Cu
- Improved Quantitative Determination of Total and Unbound Concentrations of Six Teicoplanin Components in Human Plasma by High Performance Liquid Chromatography(Miscellaneous)
- Pressure-Induced One-Dimensional Instability in (DMDCNQI)_2Cu
- Temperature-Composition Phase Diagram of the Organic Alloys, λ-BEST_2(Fe_xGa_)Cl_4, with Mixed Magnetic and Non-Magnetic Anions
- Reflectance Spectra of k-(BEDT-TTF)_2I_3:Electronic Structure of Dimeric BEDT-TTF Salts
- Temperature Dependence of the Polarized Reflectance Spectra of the θ-Type of Bis (ethylenedithio) tetrathiafulvalenium Triiodide θ-(BEDT-TTF)_2I_3:Estimation of Band Parameters
- A New Ni(dmise)_2 Complex N,N-dimethylpiperidinium[Ni(dmise)_2]_2, with Stable Metallic State
- Electrical and Structural Properties and Phase Diagram of a Molecular Superconductor β-[(CH_3)_4N][Pd(dmit)_2]_2
- Syntheses, Structures, and Molecular-Orbital Calculations of Chromium Chevrel-Type Cluster Complexes [Cr_6E_8(PR_3)_6] (E=S, PR_3=PEt_3, PMe_3; E=Se, PR_3=PEt_3, PMe_3, PMe_2Ph)
- Biochemical Characterization of Temporomandibular Joint Disc
- Conducting properties of κ-Type Molecular Metals, A New Pd(dmit)_2 Superconductor and Electron Mass Enhancement in DCNQI-Cu Systems : V-A Organic Syntheses : V Organic Superconductors
- Magnetic Properties of the Octahedral Chromium Chalcogenide Cluster Complexes [Cr_6Se_8(PEt_3)_6],[Cr_6Se_8(H)(PEt_3)_6], and [Cr_6S_8(H)(PEt_3)_6]
- Synthesis of a Molybdenum Cluster Complex [Mo_(μ_3-S)_(μ_4-S)_2(PEt_3)_] with Chevrel Phase Type Intercluster Bondings
- Synthesis and Structure of SO_2 Bridged Trinuclear Re Cluster (Et_4N) [Re_3 (μ_3-S) (μ-SO_2) (μ-S)_2Cl_6(PEt_3)_3]
- Magnetic and Thermal Properties of \lambda-(BETS)2FeCl4 System ---Fe 3d Spin in Antiferromagnetic Insulating Phase---
- Dielectric Properties of Water Chains Incorporated in Porous Coordination Polymer Crystal [Cu(C_6H_4NO_2)_2]
- Single-component Layered Molecular Conductor, [Au(ptdt)_2]
- Evidence of Charge Disproportionation in $\lambda$ Type BETS Based Organic Superconductors
- Pseudoaneurysm of the Ascending Aorta With Perforation Into the Left Atrium Presenting as Acute Heart Failure
- Synthesis, crystal structure, and physical properties of the charge-transfer complex bis[benzo[1,2-c:3,4-c':5,6-c"]trithiophene]-tetra-fluorotetracyanoquinodimethan, (BTT)2(TCNQF4).
- Orbital Effect on FFLO Phase and Energy Dissipation due to Vortex Dynamics in Magnetic-Field-Induced Superconductor \lambda-(BETS)
- Orbital Effect on FFLO Phase and Energy Dissipation due to Vortex Dynamics in Magnetic-Field-Induced Superconductor λ-(BETS)₂FeCl₄
- タイトル無し
- Crystal and molecular structure of a chelating ylide complex of palladium: [(Benzoylmethylene)diphenyl-2-(diphenylphosphino)-ethylphosphorane]dichloropalladium(II) toluene solvate.
- The crystal structure of Na2H2(Co4I3O18(OH2)6)-(Co4I3O16(OH)2(OH2)6)22H2O.
- The Crystal Structure of α-Barium 12-Tungstosilicate, α-Ba2SiW12O40·16H2O
- Reflectance spectra of the 1:1 salts of bis(methylenedithio)tetrathiafulvalene(BMDT-TTF): Estimation of the on-site coulomb energy.
- The oxidation reaction of Tl(I) to Tl(III) by the peroxodisulfate ion. I. Kinetics and mechanism in an aqueous solution.
- The intermolecular interaction of tetrathiafulvalene and bis(ethylenedithio)tetrathiafulvalene in organic metals. Calculation of orbital overlaps and models of energy-band structures.
- The crystal structure of (TMTTF)2ReO4.
- The crystal and molecular structures of bis(ethylenedithio)tetrathiafulvalene.
- Structural studies of partially oxidized one-dimensional bis(oxalato)-platinate salts containing bivalent cations: Ni0.84(Pt(C2O4)2)6H2O.
- Superconductivity and characterization of the high-pressure reaction products of carbon diselenide, CSe2.
- New multi-sulfur 1,2-dithiolene complexes. Preparation, structure, and electrochemical properties.
- Synthesis of amphiphilic porphyrins.
- A new synthetic model for myoglobin: "Tulip garden" porphyrin.
- The crystal structure of the ammonium bromide complex of 1,4,7,10,13,16-hexaoxacyclooctadecane (18-crown-6), C12H24O6 NH4Br 2H2O.
- Peierls structure of (H3O)0.33Li0.8(Pt(mnt)2)1.67H2O.
- Crystal and molecular structure of tetrabutylammonium bis(1,4-dithiin-2,3-dithiolato)nickelate(III), (Bun4N)[Ni(ddt)2].
- The crystal and band electronic structures of bis(4,5-ethylenedithio-4',5'-(vinylenedithio)tetrathiafulvalenium)hexafluorophosphate, and hexafluoroarsenate (EVT2PF6 and EVT2AsF6).
- Crystal structure and molecular structure of neutral nickel bis(5,6-dihydro-1,4-dithiin-2,3-dithiolate), Ni(dddt)2.
- The crystal structure of tetramethyltetraselenafulvalenium perrhenate, (TMTSF)(ReO4)(C2H3Cl3)0.25.
- A new phase-transfer porphyrin catalyst for the olefin epoxidation.
- Preparation and crystal structure of new gold(I) complexes linked to pyrimidines.
- 55Mn Nuclear Magnetic Resonance Studies of the Compounds with Manganese-Tin Bonds
- Synthesis and properties of 5,10,15,20-tetrakis(3,5-di-t-butyl-2-nitrophenyl)porphyrin: Conformational stabilities of the respective atropisomers and oxygenation capabilities of the iron(III) and manganese(III) complexes.
- N-allylpyrazole as a ligand. II. The preparation and reaction of some palladium(II) and platinum(II) complexes.
- Structure of Polyvanadotungstates. I. The Crystal Structure of α-(CN3H6)4V2W4O19
- 59Co quadrupole effects on the 1H,31P, and 59Co NMR spectra of HFeCo3(CO)9(P(OCH3)3)3 and the 1H NMR spectra of other derivatives.
- 1-Allylpyrazole as a ligand. V. Preparation and characterization of some iron(0) and group VI metal(0) carbonyls.
- Crystal structure of dimethyltin molybdenum tetraoxide, (CH3)2SnMoO4.
- Syntheses, spectroscopic properties, crystal structures, and antitumor activities of the optically isomeric mandelate chelates, mandelato(trans-1,2-diaminocyclohexane)platinum(II).
- Potentiometric study of equilibria in H+-MoO42-RAsO3H- (R=OH, C6H5, CH3) systems.
- Kinetic studies of the oxidation of L-ascorbic acid by the peroxodisulfate ion, and of copper(II)-catalysis.
- 119Sn-Mössbauer and 1H- and 55Mn-NMR Spectroscopic Studies of a Series of Compounds, R3−xXxSn-Mn(CO)5
- Olefin epoxidation catalyzed by sterically bulky metalloporphyrins(metal=Fe,Mn) by use of sodium hypochlorite as an oxygen source. A kinetic study.
- Molecular and crystal structure of hydrido(tricarbonyl)bis(triphenylphosphine)manganese(I), HMn(CO)3[P(C6H5)3]2.
- The Crystal Structure of Sodium Molybdate Dihydrate, Na2MoO4·2H2O
- Structural studies of commensurate Peierls state of Rb1.67[Pt(C2O4)2] 1.5H2O.
- N-allylprazole as a ligand. III. The crystal and molecular structure of (1-allyl-3,5-dimethylpyrazole)copper(I) chloride.
- Band-structure parameters of organic conductors, TSeT2Cl,TTT2I3, and TSeT2SCN.
- The crystal structure of .ALPHA.-K8SiW11O39 13H2O.
- Single-component Magnetic Molecular Conductor [Fe(dmdt)_2](dmdt:dimethyltetrathiafulvalenedithiolate
- Dielectric Propersites of the Charge-transfer Complex of Phenothiazine and Trinitrobezene