Metal-catalyzed organic photoreactions. Photoreactions of compounds containing a carbon-oxygen or carbon-nitrogen multiple bond with alcohols in the presence of titanium(IV) chloride or uranyl chloride.
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概要
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α,β-Unsaturated carbonyl compounds and esters, cyclopropyl ketones, β-diketones, Schiff's bases, and nitriles were irradiated in several alcohols in the presence of titanium(IV) chloride or uranyl chloride. In the titanium(IV) chloride-catalyzed reactions, the α-carbon atom of the primary alcohols underwent a bond formation, generally with the C=X (or C≡N) carbon atom of the substrates, while the bond formation occurred on a C=C carbon atom of the substrates in the uranyl chloride-catalyzed reactions. The reactions were examined under several conditions, and a possible scheme for the reactions was suggested.
- 公益社団法人 日本化学会の論文
著者
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Yamamura Shigeo
Department Of Clinical Pharmacy Toho Univeristy
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Ito Osamu
Department Of Agricultural Chemistry University Of Tokyo
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Sato Tadashi
Department Of Applied Chemistry Faculty Of Science And Engineering Waseda Uiversity
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Imamura Takashi
Department of Applied Chemistry, Waseda University
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Miyahara Masayuki
Department of Applied Chemistry, Waseda University
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Hasegawa Kazumi
Department of Applied Chemistry, Waseda University
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Yoshiie Shigeo
Department of Applied Chemistry, Waseda University
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