Metal-catalyzed organic photoreactions. Iron(III)-catalyzed photoreactions of aldo- and ketohexoses.
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概要
- 論文の詳細を見る
Under UV irradiation in the presence of iron(III) chloride or iron(III) triflate in pyridine, D-glucose, D-mannose, and D-galactose underwent a selective bond cleavage at the C1–C2 position, producing 4-<I>O</I>-formyl-D-arabinopyranose and 4-<I>O</I>-formyl-D-lyxopyranose. D-Fructose, under the same conditions, gave arabino-γ-lactone. The reaction was interpreted in terms of the photoinduced electron transfer within a chelate of iron ion with the carbohydrate molecule.
- 公益社団法人 日本化学会の論文
著者
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Sato Tadashi
Department Of Applied Chemistry Faculty Of Science And Engineering Waseda Uiversity
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Tomita Isao
Department Of Biotechnology Graduate School Of Engineering Osaka University
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Ichikawa Shuji
Department of Applied Chemistry, Waseda University
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Hosaka Akira
Department of Applied Chemistry, Waseda University
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