Metal-catalyzed organic photoreactions. The photooxidation of vinylsilanes and vinyl sulfides inthe presence of iron(III) chloride, and the regioselective synthesis of .ALPHA.-chloro ketones.

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概要

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• The irradiation of a pyridine solution of vinylsilanes or vinyl sulfides in the presence of iron(III) chloride under oxygen produced α-chloro ketones, with a carbonyl group at the olefinic carbon originally bearing a silicon or sulfur atom.

• 公益社団法人 日本化学会の論文

著者

• Sato Tadashi

  Department Of Applied Chemistry Faculty Of Science And Engineering Waseda Uiversity

• Murayama Eigoro

  Department of Applied Chemistry, Waseda University

• Tonegawa Tamotsu

  Department of Applied Chemistry, Waseda University

• Naoi Kunio

  Department of Applied Chemistry, Waseda University

• Sato Tadashi

  Department of Applied Chemistry, Waseda University

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