Metal-catalyzed organic photoreactions. Titanium(IV) chloride-catalyzed photoreactions of aldohexoses.

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概要

• 論文の詳細を見る

• Under UV irradiation in the presence of titanium(IV) chloride in methanol, D-glucose, D-mannose, and D-galactose underwent a selective bond cleavage at the C5–C6 position, producing the corresponding pentodialdose derivatives. The reaction was interpreted in terms of the photoinduced electron transfer within a chelate of titanium ion with the carbohydrate molecule. The synthetic utilities of the photoproducts were discussed.

• 公益社団法人 日本化学会の論文

著者

• Takahashi Kazuo

  Department Of Advanced Medical Technology And Development Bml Inc.

• Sato Tadashi

  Department Of Applied Chemistry Faculty Of Science And Engineering Waseda Uiversity

• Ichikawa Shuji

  Department of Applied Chemistry, Waseda University

• Tanaka Masato

  Department of Applied Chemistry, Waseda University

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