The addition effect of CH3Br and CH3Cl on ignition of CH4 by shock wave.

スポンサーリンク

概要

• 論文の詳細を見る

• Ignition delay times were measured in the CH<SUB>4</SUB>–CH<SUB>3</SUB>X (X: Cl or Br)–O<SUB>2</SUB> system diluted in Ar using a shock tube. The times were shorter than those without CH<SUB>3</SUB>X, indicating that CH<SUB>3</SUB>X accelerates the ignition of CH<SUB>4</SUB>. A theoretical model including 8 elementary reactions concerning CH<SUB>3</SUB>X, with a CH<SUB>4</SUB> oxidation mechanism consisting of 93 reactions, was used to examine the role of halogen for the ignition. The compounds containing Br formed a chain reaction with CH<SUB>4</SUB> and accelerated the decomposition of CH<SUB>4</SUB>, while CH<SUB>3</SUB>Cl acted only as a fuel which was easily decomposed.

• 公益社団法人 日本化学会の論文

著者

• Takahashi Kazuo

  Department Of Advanced Medical Technology And Development Bml Inc.

• Inomata Tadaaki

  Department of Chemistry, Faculty of Science and Technology, Sophia University

• Moriwaki Takao

  Department of Chemistry, Faculty of Science and Technology, Sophia University

• Okazaki Satiko

  Department of Chemistry, Faculty of Science and Technology, Sophia University

関連論文

• Two-Dimensional Melting in a Coulomb Crystal of Dusty Plasmas
• PE-436 Catalytically Inactive Lipoprotein Lipase Overexpression Increases Insulin Sensitivity in Mice(Diabetes/Obesity/Metabolic syndrome-4 (H) PE73,Poster Session (English),The 70th Anniversary Annual Scientific Meeting of the Japanese Circulation Societ
• PE-044 Novel Regulation Pathway of the LDL Receptor Family for Migration of Vascular Smooth Muscle Cells(Atherosclerosis, basic-3 (H) PE8,Poster Session (English),The 70th Anniversary Annual Scientific Meeting of the Japanese Circulation Society)
• OJ-198 LR11, an LDL Receptor Family Member, Inhibits Adipocyte Maturation through the Induced Stabilization of Beta-catenin(Diabetes/Obesity/Metabolic syndrome-2 (H) OJ33,Oral Presentation (Japanese),The 70th Anniversary Annual Scientific Meeting of the J
• Resistin Causes Impaired Glucose Tolerance Accompanied with Decreased Insulin Sensitivities in Tissues of Mice Implanted with Resistin-overexpressing Cells (Diabetes/Obesity 6 (H), The 69th Annual Scientific Meeting of the Japanese Circulation Society)
• Enhanced Migration of Intimal Smooth Muscle Cells is Accompanied with Increased Expression of PDGF β-receptor in Explants from Rabbit Plaques (Atherosclerosis, Basic 7 (IHD), The 69th Annual Scientific Meeting of the Japanese Circulation Society)
• Subcutaneous Fat Alters Insulin Sensitivity by Regulation TNF-α Expression in Visceral Fat(Diabetes/Obesity 2 (H), The 69th Annual Scientific Meeting of the Japanese Circulation Society)
• Advanced Glycation End Products in Obesity and Insulin Resistance(Diabetes/Obesity 9 (H), The 69th Annual Scientific Meeting of the Japanese Circulation Society)
• LR11, an LDL Receptor Gene Family Member, is a Novel Regulator of Smooth Muscle Cell Migration(Atherosclerosis, Basic 10 (IHD), The 69th Annual Scientific Meeting of the Japanese Circulation Society)
• Clinical Features of Familial Hypercholesterolemia in Japan in a Database from 1996-1998 by the Research Committee of the Ministry of Health, Labour and Welfare of Japan
• Mutations in Japanese Subjects with Primary Hyperlipidemia : Results from the Research Committee of the Ministry of Health and Welfare of Japan since 1996
• PE-315 Vascular Effects of TAK-559, a New Potent Dual Activator of PPAR α and γ, In Hypercholesterolemic Rabbits(Atherosclerosis, Basic 4 (IHD) : PE54)(Poster Session (English))
• OJ-194 Effect of Pitavastatin on Recruitment of Bone Marrow-Derived Smooth Muscle Cells in Atheroma of ApoE-deficient Mice(Atherosclerosis, Basic 2 (IHD) : OJ22)(Oral Presentation (Japanese))
• FRS-125 Increased levels of circulating vascular endothelial growth factor is associated with visceral fat accumulation(Metabolic Syndrome (H) : FRS15)(Featured Research Session (English))
• Silent Brain Infarction and Subcortical White Matter Lesions Increase the Risk of Stroke and Mortality : A Prospective Cohort Study
• Effect of One-Shot Intravenous 0.42 Mega Unit Urokinase Therapy in Patients With Acute Ischemic Stroke
• Deterioration of Vascular Dementia Caused by Recurrent Multiple Small Emboli from Thoracic Aortic Atheroma
• Enhanced expression of the LDL receptor family member LR11 increases migration of smooth muscle cells in vitro
• Effects of tributyltin on the emotional behavior of C57BL/6 mice and the development of atopic dermatitis-like lesions in DS-Nh mice
• Cyclophosphamide decreases the number, percentage and the function of CD25^+ CD4^+ regulatory T cells, which suppress induction of contact hypersensitivity
• Two Cases of Contact Dermatitis due to 1, 3-Butylene Glycol
• Herpesvirus DNA in Peripheral Blood Mononuclear Cells of Some Patients with Meniere's Disease
• Genetic control of delayed-type hypersensitivity to gold antigens in mice
• C-514T polymorphism in the hepatic lipase gene determines plasma lipid levels in the subjects with familial combined hyperlipidemia
• Influence of Japanese cedar pollen on atopic dermatitis
• Structure Changes of Coulomb Crystal in a Carbon Fine-Particle Plasma
• Simple Hexagonal Coulomb Crystal near a Deformed Plasma Sheath Boundary in a Dusty Plasma
• Different Insulin Sensitivities of Aorta and Muscle in TNF-alpha Overexpression Model by the Transplantation of Cultural Cells
• Increased circulating MDA-LDL levels in patients with coronary artery diseases and its association with the peak sizes of LDL particles
• Positive family history for CHD and "midband lipoproteins" are potential risk factors of carotid atherosclerosis in familial hypercholesterolemia
• A case of contact dermatitis due to diphenhydramine hydrochloride and fradiomycin sulfate
• MECHANISM OF ANTI-ALLERGIC DRUGS ON HISTAMINE RELEASE FROM MAST CELLS
• Study on Dynamic Properties of a Concrete Filled Tubular (CFT) Arch Bridge Constructed in China
• Influence of Cable Loosening on Nonlinear Parametric Response of Inclined Cables
• Analysis of Local Vibrations in the Stay Cables of an Existing Cable-stayed Bridge under Wind Gusts
• Effect of Thermal Aging on Breakdown Strength of Polyethylene
• Etching of High-k Dielectric HfO2 Films in BCl3-Containing Plasmas Enhanced with O2 Addition
• Two cases of allergic contact dermatitis due to a topical over the counter drug for sterilizing
• A Model Analysis of Feature Profile Evolution and Microscopic Uniformity during Polysilicon Gate Etching in Cl2/O2 Plasmas
• S8-6 Environmental chemicals and allergic disease(Effects of environmental pollution on bronchial asthma and atopic disease,English session)
• Plasma Diagnostics and Thrust Performance Analysis of a Microwave-Excited Microplasma Thruster
• Characterization of Inductively-Coupled RF Plasma Sources with Multiple Low-Inductance Antenna Units
• Metal-catalyzed organic photoreactions. Titanium(IV) chloride-catalyzed photoreactions of aldohexoses.
• Metabolic Syndrome Increases the Risk of Ischemic Stroke in Women
• Effects of zinc deficient diet on development of atopic dermatitis-like eruptions in DS-Nh mice
• Infrared Absorption Spectra and Normal Coordinate Analysis of Metal-DL-Tyrosine Chelates
• The addition effect of CH3Br and CH3Cl on ignition of CH4 by shock wave.
• Effect of Bromotrifluoromethane on the Ignition in Methane and Ethane-Oxygen-Argon Mixtures behind Shock Waves.
• The addition effects of methyl halides on ethane ignition behind reflected shock waves.
• Structure Changes of Coulomb Crystal in a Carbon Fine-Particle Plasma
• The transition to detonation from deflagration in ethylene-oxygen systems.
• Analysis of dermatomyositis-specific autoantibodies and clinical characteristics in Japanese patients
• Bivalent metal complexes of N,N-bis(2-hydroxyethyl)glycine.
• The addition effect of CH3I on the ignition of CH4.
• Comparison of effective impact among tonsillectomy alone, tonsillectomy combined with oral steroid and with steroid pulse therapy on long-term outcome of immunoglobulin A nephropathy

もっと見る 閉じる

スポンサーリンク