Uptake of Cu(II) Ions into α-Zirconium Phosphate-Ethylamine Intercalate and their Coordination Environment in Host-guest Matrices
スポンサーリンク
概要
- 論文の詳細を見る
Zirconium bis (monohydrogenorthophosphate) monohydrate (α-zirconium phosphate) with relatively large particle size was prepared and employed as an intercalation host for ethylamine. Solid phases with the interlayer distances of 7.6, 9.6, 10.8, and 13.9Å were observed as the intercalation proceeded. Further uptake of Cu(II) ions into the interlayer region of the intercalate was possible, and the coordination environment of Cu (II) ions was investigated by means of EXAFS and XANES. The results indicate that the Cu (II) ions were coordinated to O^- active sites rather than N atoms of the amine.
- お茶の水女子大学の論文
著者
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Nakai Izumi
Department of Applied Chemistry, Science University of Tokyo
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TOMITA Isao
Department of Pharmaceutical Sciences, University of Shizuoka
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Tomita Isao
Department Of Chemistry Faculty Of Science Ochanomizu University
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Nakai Izumi
Department Of Chemistry The University Of Tsukuba
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Nakai Izumi
Department Of Applied Chemistry Faculty Of Science Science University Of Tokyo
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Inoue Ritsuko
Department of Chemistry, Faculty of Science, Ochanomizu University
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Hasegawa Yoshitsugu
Department of Industrial Chemistry, Tokyo University of Agriculture and Technology
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Inoue Ritsuko
Department Of Chemistry Faculty Of Science Ochanomizu University:(present Address)sony Corporation
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Hasegawa Yoshitsugu
Department Of Industrial Chemistry Tokyo University Of Agriculture And Technology
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Hasegawa Yoshitsugu
Department Of Applied Chemistry Faculty Of Technology Tokyo University Of Agriculture And Technology
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Tomita Isao
Department Of Biotechnology Graduate School Of Engineering Osaka University
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