Synthesis of copper(II)-dithiooxamide complex in zirconium phosphate.
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概要
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Copper(II)–dithiooxamide (rubeanic acid) complex was synthesized in the interlayer region of zirconium phosphate. The product, called ZP–CuLra, was chracterized by chemical analysis, thermal analysis, infrared spectroscopy, and X-ray diffractometry. The chemical composition of ZP–CuLra was represented as ZrCu(H<SUB>2</SUB>NCS)<SUB>2</SUB>(PO<SUB>4</SUB>)<SUB>2</SUB>·H<SUB>2</SUB>O or ZrCu(HNCS)<SUB>2</SUB>(HPO<SUB>4</SUB>)<SUB>2</SUB>·H<SUB>2</SUB>O. The interlayer distance of ZP–CuLra was found to be 9.0 Å. By analogy with Cu(II)–rubeanic acid complex prepared in a solution, a structural model of ZP–CuLra was proposed.
- 公益社団法人 日本化学会の論文
著者
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Hasegawa Yoshitsugu
Department Of Applied Chemistry Faculty Of Technology Tokyo University Of Agriculture And Technology
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Sasaki Kaname
Department of Industrial Chemistry, Faculty of Technology, Tokyo University of Agriculture and Technology
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Kamikawaji Midori
Department of Industrial Chemistry, Faculty of Technology, Tokyo University of Agriculture and Technology
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