Syntheses of All Four Stereoisomers of Pyriculol
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概要
- 論文の詳細を見る
All four Stereoisomers of pyriculol were synthesized to assist in forming a correlation between their chemical structure and biological activity. The (R, E)-2-hydroxy-3-pentenal derivative was coupled with a lithium acetylide derivative to give a diastereomeric mixture of the acetylenic alcohol, which led to the antipode of pyriculol and its 3-epimer. Similarly obtained were the natural pyriculol and its 3-epimer from the (S)-isomer of this aldehyde.
- 社団法人 日本農芸化学会の論文
著者
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Murayama Tetsuya
Department Of Applied Biological Chemistry Faculty Of Agriculture Tohoku University
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Yamashita Kyohei
Department Of Agricultural Chemistry Faculty Of Agriculture Tohoku University
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Sugiyama Takeyoshi
Department Of Agricultural Chemistry Faculty Of Agriculture Tohoku University
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Watanabe Masashi
Department Of Anesthesiology Dokkyo University School Of Medicine
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SUZUKI Masanobu
Department of Agricultural Chemistry, Faculty of Agriculture, Tohoku University
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MURAYAMA Tetsuya
Department of Agricultural Chemistry, Faculty of Agriculture, Tohoku University
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