Ruthenium–amine complexation for constructing self-assembled molecular films
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概要
- 論文の詳細を見る
A redox active self-assembled monolayer consisting of ethylenediamine moieties coordinated to RuIII ions was prepared through a vapor phase silane coupling of N-(2-aminoethyl)-3-aminopropyltrimethoxysilane (AEAPS) molecules onto a SiO2/Si substrate, followed by complexation of RuIII ions in an aqueous RuCl3 solution. A similar SAM with 3-aminopropyltriethoxysilane did not provide surface RuIII-complex, indicating that chelation ability plays a key role in immobilizing RuIII ions at the surface. The RuIII chelated AEAPS-SAM gave a couple of RuIII/RuIV redox peaks at +1.0 and －0.1 V vs. Ag/AgCl (3 mol dm－3 NaCl).
- 2008-05-15
著者
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Sugimura H
Department Of Materials Processing And Engineering Graduate School Of Engineering Nagoya University
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Sugimura Hiroyuki
Tsukuba Research Laboratory Nikon Co.:(present Address)depeartrnent Of Materials Processing Enginerr
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Sugimura Hiroyuki
Department of Materials Science and Engineering, Graduate School of Engineering, Kyoto University, Sakyo-ku, Kyoto 606-8501, Japan
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Murase Kuniaki
Department of Materials Science and Engineering, Kyoto University, Sakyo, Kyoto 606-8501, Japan
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