Sustainable Electrodeposition of ZnO by a Galvanic Contact Method
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概要
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The galvanic contact deposition of ZnO was carried out by immersing a conductive substrate short-circuited with a Zn rod into O2-saturated aqueous Zn(ClO4)2 solutions, and the deposition behaviors were investigated in comparison with that in Zn(NO3)2. The dissolution of the Zn rod in the Zn(ClO4)2 solutions supplied a continuous and almost constant current to the substrate, allowing the cathodic electrodeposition of ZnO without an external power and by-products. The morphology of the resulting ZnO depended on the Zn(ClO4)2 concentration. In contrast, a much smaller current was observed in the Zn(NO3)2 solution, and little ZnO was deposited.
著者
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Shinagawa Tsutomu
Osaka Municipal Technical Res. Inst. Osaka Jpn
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Murase Kuniaki
Department of Materials Science and Engineering, Kyoto University, Sakyo, Kyoto 606-8501, Japan
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