FLUOROKINOSHITALITE AND FLUOROTETRAFERRIPHLOGOPITE : NEW SPECIES OF FLUORO-MICA FROM BAYAN OBO, INNER MONGOLIA, CHINA
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概要
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Two new species of F-mica, fluorokinoshitalite (BaMg_3Al_2Si_2O_<10>F_2) and fluorotetraferriphlogopite (KMg_3Fe^<3+>Si_3O_<10>F_2) occur in Bayan Obo, Inner Mongolia, China. They form subhedral to euhedral platy crystals in metamorphosed carbonate rocks. They are associated with phlogopite, yangzhumingite, and rare earth minerals such as bastnasite-(Ce), cordylite-(Ce), monazite-(Ce), fluorbritholite-(Ce) and huanghoite-(Ce). Fluorokinoshitalite is transparent and colorless with white streak and pearly luster. Cleavage is perfect on {001}. The calculated density is 3.235g cm^<-3>. Fluorotetraferriphlogopite is brown in color with white to pale brown streak. It is transparent showing pearly luster and perfect cleavage on {001}. The hardness is 3-4 on the Mohs scale. The calculated density is 2.966g cm^<-3>. This mineral is optically biaxial (-) with n=1.576 (min.)-1.582 (max.). It shows reverse pleochroism (Z'=colorless, X'=light brown). Electron microprobe analyses with SIMS for Li gave empirical formulae (based on 12 anions); (Ba_<0.56>Na_<0.25>K_<0.06>)(Mg_<2.76>Fe^<2+>_<0.14>Ti_<0.01>) (Si_<2.73>Al_<1.15>Fe^<3+>_<0.12>)O_<10>[F_<1.72>(OH)_<0.28>] and (K_<0.94>Na_<0.02>Ba_<0.01>)(Mg_<2.62>Li_<0.15>Fe^<+2>_<0.14>_Mn_<0.01>)(Si_<3.33>Fe^<3+>_<0.66>Al_<0.01>)O_<10>[F_<1.65>(OH)_<0.35>] for fluorokinoshitalite and fluorotetraferriphlogopite, respectively. The lattice parameters were refined in the monoclinic system (C2/m) with the XRD data obtained with an IP-Gandolfi camera as; a=5.3161 (11), b=9.2082(15), c=10.044(2) Å, β=100.158(18)°, V=483.97(17) Å^3 (fluorokinoshitalite) and a=5.325(3), b=9.217(5), c=10.192(7) Å, β=100.03(5)°, V=492.6(5) Å^3 (fluorotetraferriphlogopite).
著者
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横山 一己
国立科博・地学
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MATSUBARA Satoshi
Department of Geology and Paleontology, National Museum of Nature and Science
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MIYAWAKI Ritsuro
Department of Geology and Paleontology, National Museum of Nature and Science
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横山 一巳
Department of Geology and Paleontology, National Science Museum
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Shimizu Masaaki
Department Of Earth Sciences Faculty Of Science Toyama University
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Matsubara Satoshi
Department Of Geology And Paleontology National Museum Of Nature And Science
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Shimazaki Hidehiko
Department Of Geology And Paleontology National Museum Of Nature And Science
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Shimazaki Hidehiko
Department Of Geology And Paleonotology National Museum Of Nature And Science
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横山 一己
Department Of Geology National Science Museum Shinjuku-ku Tokyo
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Shigeoka Masako
Department Of Geology And Paleontology National Museum Of Nature And Science
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Miyawaki R
Department Of Geology And Paleontology National Museum Of Nature And Science
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Miyawaki Ritsuro
Department Of Geology And Paleontology National Science Museum
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Yurimoto Hisayoshi
Department Of Natural History Sciences Hokkaido University
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Yurimoto Hisayoshi
Department Of Earth And Planetary Sciences Tokyo Institute Of Technology
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Shimazaki Hidehiko
Department Of Geology And Paleontology National Museum Of Nature And Science:the University Of Tokyo
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Yokoyama Kazumi
Department Of Geology And Paleontology National Museum Of Nature And Science
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Yokoyama Kazumi
Dep. Of Geology And Paleontology National Museum Of Nature And Sci.
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YANG ZHUMING
Institute of Geology and Geophysics, Chinese Academy of Sciences
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ZHANG PEISHAN
Institute of Geology and Geophysics, Chinese Academy of Sciences
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Yang Zhuming
Institute Of Geology And Geophysics Chinese Academy Of Sciences
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Zhang Peishan
Institute Of Geology And Geophysics Chinese Academy Of Sciences
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Miyawaki Ritsuro
Department Of Geology And Paleontology National Museum Of Nature And Science
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横山 一己
国立科学博物館
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