Tokyoite, Ba_2Mn^<3+>(VO_4)_2(OH), a new mineral from the Shiromaru mine, Okutama, Tokyo, Japan
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概要
- 論文の詳細を見る
Tokyoite, Ba2Mn3+(VO4)2(OH), the Mn3+-analogue of gamagarite, is found from the Shiromaru mine, Okutama, Tokyo, Japan. It is monoclinic, P21/m, a = 9.10(4), b = 6.13(2), c = 7.89(5) Å, β = 112.2(5)°, Z = 2. The strongest lines in the powder X-ray diffraction pattern are 3.73 (15) (111), 3.31 (100) (112), 3.08 (20) (020), 3.00 (16) (301, 212, 102), 2.90 (19) (120), 2.80 (62) (121, 300), 2.16 (18) (321), 1.963 (15) (204). Electron microprobe analysis gave V2O5 31.77, SiO2 0.15, Al2O3 0.07, Fe2O3 2.33, Mn2O3 11.27, CaO 0.07, BaO 51.91, SrO 0.22, Na2O 0.13, H2O (calc.) 1.59, total 99.51 wt. %, and lead to the empirical formula, (Ba1.92Na0.02Sr0.01Ca0.01)Σ1.96(Mn3+0.81Fe3+0.17Al0.01)Σ0.99[(V1.99Si0.01)O7.92](OH)1.00 on the basis of V + Si = 2 and (OH) = 1. It is translucent and black red in color with a vitreous luster. The streak is dark brownish red and cleavage is not observed. The Mohs hardness is about 4 to 4.5. The calculated density is 4.62 g/cm3. It has distinct pleochroism, from reddish orange to dark brownish red in thin section and the calculated mean refractive index is 2.03. It occurs as irregular grains under 15 μm, and the aggregates are up to 250 μm wide in association with braunite, hyalophane and tamaite. The mineral is formed under the later stage activity of low grade metamorphism.
- 2004-12-01
著者
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MATSUBARA Satoshi
Department of Geology and Paleontology, National Museum of Nature and Science
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MIYAWAKI Ritsuro
Department of Geology and Paleontology, National Museum of Nature and Science
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Shimizu Masaaki
Department Of Earth Sciences Faculty Of Science Toyama University
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Matsubara Satoshi
Department Of Geology And Paleontology National Museum Of Nature And Science
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Shigeoka Masako
Department Of Geology And Paleontology National Museum Of Nature And Science
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Miyawaki R
Department Of Geology And Paleontology National Museum Of Nature And Science
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Miyawaki Ritsuro
Department Of Geology And Paleontology National Science Museum
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Yokoyama Kazumi
Department Of Geology And Paleontology National Museum Of Nature And Science
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Yokoyama Kazumi
Dep. Of Geology And Paleontology National Museum Of Nature And Sci.
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IMAI Hiroyuki
Yamanashi Institute of Gemmology and Jewelry Arts
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Miyawaki Ritsuro
Department Of Geology And Paleontology National Museum Of Nature And Science
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Shimizu Masaaki
Department of Chemistry, Faculty of Science, Nagoya University
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