Structures of Two Novel Sesquiterpenoids Formed by the Lead Tetraacetate Oxidation of β-Caryophyllene(Organic Chemistry)
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概要
- 論文の詳細を見る
Two crystalline minor products (14 and 15) were newly obtained by the oxidation of β-caryophyllene (1) with lead tetraacetate. The structures were determined as 4,4-dimethyltricyclo-[6.3.2.0^<2.5>]tridec-8-en-1-ol (14) and 4,4-dimethyl-9-oxatetracyclo[6.4.2.0^<2.5>.0^<8.10>]tridecan-1-ol (15) by HR-MS, LR-MS, IR, ^1H-NMR, ^<13>C-NMR, and single crystal X-ray analysis data. Products 14 and 15 are novel sesquiterpenes.
- 社団法人日本農芸化学会の論文
- 1989-11-23
著者
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Koyama Y
Kikkoman Corp. Chiba Jpn
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MATSUBARA Yoshiharu
Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University
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Uchida Toshikazu
Department Of Applied Chemistry Faculty Of Science And Engineering Kinki University
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Koyama Yuzo
Research Institute For Science And Technology Kinki University
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Matsubara Yoshiharu
Department Of Applied Chemistry Faculty Of Science And Engineering Kinki University
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MATSUBARA Yoshiharu
Department of Agricultural Chemistry, Faculty of Agriculture, Kinki University
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